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- W4308467055 abstract "Abstract Reducing inter-spin distance can enable effective magnetic interactions to realize outstanding magnetic properties, which, however, remains rather challenging. Here, an unprecedented 3d-4f metal cluster (Dy2VN) was constructed inside a C80 cage, affording a heretofore unseen metallofullerene containing both paramagnetic 3d and 4f metal ions. Significantly suppressed 3d-4f (Dy-V) distances, due to the unique cage confinement effect, are directly recorded by crystallographic and theoretical analysis of Dy2VN@Ih(7)-C80. Consequently, superior magnetic coupling (Jtotal, Dy-V = 53.30 cm-1; Jtotal, Dy-Dy = -18.75 cm-1) is obtained, leading to a record-high magnetic blocking temperature among all reported 3d-4f single-molecule magnets and huge coercive field of 2.73 Tesla. Our work puts forth a new class of single-molecule magnets with both paramagnetic 3d and 4f metals confined in a fullerene cage, of which superior and tunable magnetic properties are envisioned thanks to the unique cage confinement effect and the diverse composition of the entrapped magnetic core." @default.
- W4308467055 created "2022-11-12" @default.
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- W4308467055 date "2022-11-07" @default.
- W4308467055 modified "2023-09-30" @default.
- W4308467055 title "A hard molecular nanomagnet from confined paramagnetic 3d-4f spins inside a fullerene cage" @default.
- W4308467055 doi "https://doi.org/10.21203/rs.3.rs-2240737/v1" @default.
- W4308467055 hasPublicationYear "2022" @default.
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