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- W4308486096 abstract "In this work, we report manganese porphyrin complexes for the electrocatalytic vicinal diazidation of alkenes with sodium azide. This protocol shows improved practicality over our previous work using MnBr2 catalysis in the following aspects: (1) it requires substantially lower catalyst loading (as low as 0.3 mol %), which reduces the formation of metal azide complexes and simplifies product purification; (2) the introduction of a neutral aqueous buffer prevents the generation of toxic hydrazoic acid, contributing to a safer experimental procedure; (3) the catalytic system displays improved reactivity toward unactivated terminal alkenes. Mechanistic studies support the roles of second-sphere hydrogen-bond donors in stabilizing key reaction intermediates." @default.
- W4308486096 created "2022-11-12" @default.
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- W4308486096 date "2022-11-03" @default.
- W4308486096 modified "2023-10-16" @default.
- W4308486096 title "Electrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors" @default.
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- W4308486096 doi "https://doi.org/10.1021/acscatal.2c05186" @default.
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