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• W4308488031 endingPage "120690" @default.
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• W4308488031 abstract "• Two hydrophobic hydration monolayers: an inner ordered gaseous layer and an outer electro-frozen layer. • New equations for calculating solubilities of hydrophobic gases in water and n-alkanes. • Interfacial structure of 4 crystalline layers of clathrate is suggested. • Interfacial tensions and internal pressures of gas/water and gas/n-alkanes are calculated. • Interfacial tension of nano surface is calculated. This essay covers aspects concerning with the hydrophobic hydration of apolar gas (H 2 , He, Ne, N 2 , O 2 , Ar, CH 4 , C 2 H 6 , C 3 H 8 , n-C 4 H 10 and i-C 4 H 10 ), solubilities in water and hexadecane, interfacial tensions of water/gases, hexadecane/gases and n-alkane (C7-C18)/N 2 and O 2 interface at 298K. The main results are: 1) Two water layers of hydration should be taken into account. 1 st layer closest to an apolar molecule is hot ice or ordered gas and independent to 2 nd layer. Water dipoles orderly, dramatically and endlessly rotate and create a negative electric field, in turn electro-freeze 2 nd layer. 2) Entropic change of H + partition between 2 nd layer and bulk water leads to the ionization of water. 3) Interfacial tension and internal pressure of 2 nd layer caused by electric potential are -13.9 mJ/m 2 and -54 MPa, respectively. 4) Thermodynamic process for solvation: i) isothermally compressing gas to the solid state to take in all the kinetic energy of gas for creating a cavity with 4 free HBs; ii) mixing the hydrates (solvated entities) with water (alkane) as mixing of ideal gas. 5) Gas collides with surface to create the crystalline foam consisting of 4 layers of hydrates or solvated entities. The solubilities of gases, the interfacial tension and internal pressure of water (alkane)/gas interface are calculated with quite appraisable results." @default.
• W4308488031 created "2022-11-12" @default.
• W4308488031 creator A5005934646 @default.
• W4308488031 date "2022-12-01" @default.
• W4308488031 modified "2023-09-23" @default.
• W4308488031 title "On the hydrophobic hydration, solvation and interface: A thought essay (I)" @default.
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• W4308488031 doi "https://doi.org/10.1016/j.molliq.2022.120690" @default.
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