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• W4308492588 abstract "The functionalization of graphene with inorganic nanomaterials has attracted widespread attention because of its enhanced electrical and electrochemical properties. The manufacturing of three-dimensional (3D) structures of functionalized graphene-based materials, exhibiting geometric advantages to improve performance, allows the extension of their application fields. Herein, we demonstrate a practical 3D printing approach to fabricate silver nanoparticle (AgNP)-decorated graphene (AgNP–graphene) 3D microarchitectures. The approach consists of sequential processes: (i) direct-ink-writing (DIW) of graphene microarchitecture with ink including graphene flakes and silver nitrate (AgNO 3 ), and (ii) chemical reduction of Ag ions with thermal treatment. AgNPs with a size distribution of 60 ± 15.26 nm are decorated uniformly on the printed graphene objects, exhibiting a conductivity of ~4.78 S∙cm -1 . Various AgNPs-graphene 3D microarchitectures are successfully printed, such as a Peano curve, Gosper curve, and volumetric structure of a five-pointed star polygon and butterfly. Potential electronic applications in flexible electronic devices, including resistance transducers for chloride ion (Cl - ) sensors and 3D grids for electromagnetic interference (EMI) shielding, are demonstrated. This technique presents a facile approach for manufacturing AgNP-graphene 3D microarchitectures and has potential for applications in the field of advanced printed electronics. • A simple three-dimensional (3D) printing approach is discussed to produce silver nanoparticle (AgNP)-decorated graphene (AgNP–graphene) 3D microarchitectures. • Graphene microarchitectures are produced by a direct-ink-writing with ink including graphene flakes and silver nitrate. • AgNPs with a size distribution of 60 ± 15.26 nm are formed on the printed graphene microarchitectures by a chemical reduction of Ag ions with thermal treatment. • The manufacturing of AgNP–graphene 3D structures, exhibiting geometric advantages to improve performance, allows the extension of their application fields." @default.
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• W4308492588 date "2022-12-01" @default.
• W4308492588 modified "2023-10-14" @default.
• W4308492588 title "Three-dimensional printing of silver nanoparticle-decorated graphene microarchitectures" @default.
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• W4308492588 doi "https://doi.org/10.1016/j.addma.2022.103249" @default.
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