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- W4308532827 abstract "Bi2Te3 nanostructures were synthesized through a facie hydrothermal method. A comprehensive and systematic investigations on the effect of pH, on the purity, crystallinity, size and morphology of synthesized nanostructures were carried out. Bi2Te3 nanoparticles, nanoplates, nanoflowers and nanotubes were obtained at different pH ranges. Based on the XRD, FESEM, EDAX and HRTEM observations, a detailed growth mechanism is proposed, which shed light on the formation of primary Bi2Te3 nanoplates and the hierarchical nanostructures. Oswald ripening process is identified as the dominant growth mechanism at lower pH values. Under alkaline environment, an imperfect oriented attachment mechanism leads to evolution of nanostructures with diverse morphology from primary Bi2Te3 nanoplates. The three-dimensional nanostructures offer themselves as good thermoelectric materials due to their reduced thermal conductivity owing to the phonon scattering centres. In addition, the quantum confinement effect and the morphological fluctuation in the obtained nanostructures may improve the thermoelectric performance by resulting modified energy band structure." @default.
- W4308532827 created "2022-11-12" @default.
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- W4308532827 creator A5061118026 @default.
- W4308532827 date "2023-01-01" @default.
- W4308532827 modified "2023-09-25" @default.
- W4308532827 title "Deep tuning of Bi2Te3 nanostructures suitable for thermoelectric waste heat recovery: The impact of pH on crystal growth in hydrothermal synthesis" @default.
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- W4308532827 doi "https://doi.org/10.1016/j.mseb.2022.116090" @default.
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