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- W4308554889 abstract "Here, a hexanuclear Co6(μ3-OH)6 cluster-based metal–organic framework (MOF), [Co6(μ3-OH)6(BTB)2(bpy)3]n (JXNU-15) (bpy = 4,4′-bipyridine), with the 1,3,5-tri(4-carboxyphenyl)benzene (BTB3–) ligand was synthesized for the challenging propadiene/propylene separation. The combination of a large pore volume and a suitable pore environment boosts the significantly high propadiene (C3H4) uptake (311 cm3 g–1 at 298 K and 100 kPa) for JXNU-15. An amine-functionalized MOF of JXNU-15(NH2) was further obtained with the 1,3,5-tri(4-carboxyphenyl)benzene analogue of 3,3″-diamino-5′-(3-amino-4-carboxyphenyl)-[1,1′:3′,1″-terphenyl]-4,4″-dicarboxylic ligand. The comparative studies of propadiene/propylene(C3H4/C3H6) separation performance between isostructural JXNU-15 and JXNU-15(NH2) are provided. JXNU-15(NH2) exhibits an impressive C3H4 capacity at low pressures with 69.1 cm3 g–1 at 10 kPa, which is twice that of JXNU-15 under the same conditions. Moreover, the separation selectivity of JXNU-15(NH2) is 1.3-fold higher as compared to JXNU-15. JXNU-15(NH2) with enhanced C3H4/C3H6 separation performance was elegantly illustrated by gas separation experiments and theoretical simulations. This work presents an amine-functionalized strategy for the enhancement of the C3H4/C3H6 separation performance of MOF." @default.
- W4308554889 created "2022-11-12" @default.
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- W4308554889 date "2022-11-07" @default.
- W4308554889 modified "2023-10-15" @default.
- W4308554889 title "Enhancement of Propadiene/Propylene Separation Performance of Metal–Organic Frameworks by an Amine-Functionalized Strategy" @default.
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- W4308554889 doi "https://doi.org/10.1021/acs.inorgchem.2c03276" @default.
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