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- W4308559085 endingPage "129036" @default.
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- W4308559085 abstract "Superhydrophobic polymer coatings are receiving special attention for industrial applications due to their multifunctionality behaviour. The advancement in nanotechnology has made it easier to design and fabricate nano-textured superhydrophobic coating on metal surfaces, even though adhesion and durability still remain a challenge. Therefore, the present study focuses on a novel bilayer coating approach for fabricating thermally stable, abrasion tolerant, multi-functional, superhydrophobic surface coating through the chemical bonding at the interface of hydroxy terminated polydimethylsiloxane modified cardanol-based polyurethane and silane grafted ZnO nanoparticles. The silane grafting to the ZnO surface has been confirmed by FT-IR, EDX, and XPS analysis. In addition, the change in crystallinity of unmodified and modified ZnO-based HTPDMS-CPU have been studied using XRD analysis. The superhydrophobic surface coating showed a high contact angle of 151° and contact angle hysteresis of 7° which got reduced after 10 cycles of abrasion to 133° and 12°, respectively. The silane groups at the surface allow ZnO to disperse uniformly and get exposed through the polymer coating while forming the micro/nano scale morphology. Furthermore, the anticorrosion parameters of the superhydrophobic bilayer coating showed corrosion current density (Icorr) value of order 10−9 (A.cm2) and corrosion potential (Ecorr) value of −0.351 (V) with inhibition efficiency (ƞ) of 99.5 % on mild steel. Thus, the superhydrophobicity, along with the excellent anticorrosion properties of this bilayer coating with a strong interface, chemical resistance and thermal stability elaborates its applicability in various fields." @default.
- W4308559085 created "2022-11-12" @default.
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- W4308559085 date "2022-12-01" @default.
- W4308559085 modified "2023-09-26" @default.
- W4308559085 title "Design and fabrication of nano textured superhydrophobic and anti-corrosive silane-grafted ZnO/bio-based polyurethane bilayer coating" @default.
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- W4308559085 doi "https://doi.org/10.1016/j.surfcoat.2022.129036" @default.
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