Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308562693> ?p ?o ?g. }
- W4308562693 endingPage "731" @default.
- W4308562693 startingPage "724" @default.
- W4308562693 abstract "Sodium-ion batteries (SIBs) are the promising candidate in grid systems owing to the wide distribution and abundance of sodium resources. However, the charge storage mechanism and size-effect of the active materials for SIBs remain largely unexplored. Herein, we synchronously investigate the electrochemical properties and structural evolutions of Li4Ti5O12 (LTO) anode for Li+ and Na+ storage, along with the nano-size effect on their charge storage behaviors. Through detailed kinetic analysis, it is found the Li+ storage in LTO is diffusion-controlled in bulk and shows increased surface-controlled contributions when the size is reduced to 18 nm. In comparison, for the Na+ storage, the domination step is surface-controlled in all the sizes of LTO from 260 to 18 nm, with over 55% contribution even at the low sweep rate of 0.1 mV s−1. The limited near-surface reaction region and low diffusion kinetics determine the surface-controlled Na+ storage behaviors and the specific capacities. The suitable size of LTO-18 nm anode displays a high capacity of ∼140 mAh g−1 (at 0.05 A g−1, ∼0.29C), high-rate capability (42 mAh g−1 at ∼57C), and long-term cycling stability (over 1200 cycles). Our finding provides insights into a precise design of nanomaterials for high-power sodium-ion storage devices." @default.
- W4308562693 created "2022-11-12" @default.
- W4308562693 creator A5003008613 @default.
- W4308562693 creator A5017164385 @default.
- W4308562693 creator A5020147939 @default.
- W4308562693 creator A5022227925 @default.
- W4308562693 creator A5048213094 @default.
- W4308562693 creator A5069483701 @default.
- W4308562693 creator A5083693075 @default.
- W4308562693 creator A5085619057 @default.
- W4308562693 date "2023-01-01" @default.
- W4308562693 modified "2023-10-11" @default.
- W4308562693 title "Surface-controlled sodium-ion storage mechanism of Li4Ti5O12 anode" @default.
- W4308562693 cites W1673406831 @default.
- W4308562693 cites W1970320842 @default.
- W4308562693 cites W2001574153 @default.
- W4308562693 cites W2004432407 @default.
- W4308562693 cites W2019089799 @default.
- W4308562693 cites W2020124958 @default.
- W4308562693 cites W2020609369 @default.
- W4308562693 cites W2022301776 @default.
- W4308562693 cites W2025811002 @default.
- W4308562693 cites W2034759033 @default.
- W4308562693 cites W2041124455 @default.
- W4308562693 cites W2091621042 @default.
- W4308562693 cites W2117499552 @default.
- W4308562693 cites W2123221486 @default.
- W4308562693 cites W2136267299 @default.
- W4308562693 cites W2136822440 @default.
- W4308562693 cites W2154232712 @default.
- W4308562693 cites W2158463469 @default.
- W4308562693 cites W2255686650 @default.
- W4308562693 cites W2310280223 @default.
- W4308562693 cites W2312255598 @default.
- W4308562693 cites W2326604655 @default.
- W4308562693 cites W2333828825 @default.
- W4308562693 cites W2334524689 @default.
- W4308562693 cites W2404711663 @default.
- W4308562693 cites W2514843481 @default.
- W4308562693 cites W2604330414 @default.
- W4308562693 cites W2763721492 @default.
- W4308562693 cites W2792762764 @default.
- W4308562693 cites W2902441058 @default.
- W4308562693 cites W2915574732 @default.
- W4308562693 cites W2978404528 @default.
- W4308562693 cites W2990494401 @default.
- W4308562693 cites W2992138817 @default.
- W4308562693 cites W3013252775 @default.
- W4308562693 cites W3027847271 @default.
- W4308562693 cites W3037830571 @default.
- W4308562693 cites W3086978961 @default.
- W4308562693 cites W3096999913 @default.
- W4308562693 cites W3151201888 @default.
- W4308562693 cites W3177188809 @default.
- W4308562693 cites W3189586542 @default.
- W4308562693 cites W3217423734 @default.
- W4308562693 cites W4220866247 @default.
- W4308562693 cites W4224884362 @default.
- W4308562693 cites W4225712263 @default.
- W4308562693 cites W4232160793 @default.
- W4308562693 cites W4282939719 @default.
- W4308562693 cites W4285169158 @default.
- W4308562693 doi "https://doi.org/10.1016/j.ensm.2022.11.017" @default.
- W4308562693 hasPublicationYear "2023" @default.
- W4308562693 type Work @default.
- W4308562693 citedByCount "10" @default.
- W4308562693 countsByYear W43085626932023 @default.
- W4308562693 crossrefType "journal-article" @default.
- W4308562693 hasAuthorship W4308562693A5003008613 @default.
- W4308562693 hasAuthorship W4308562693A5017164385 @default.
- W4308562693 hasAuthorship W4308562693A5020147939 @default.
- W4308562693 hasAuthorship W4308562693A5022227925 @default.
- W4308562693 hasAuthorship W4308562693A5048213094 @default.
- W4308562693 hasAuthorship W4308562693A5069483701 @default.
- W4308562693 hasAuthorship W4308562693A5083693075 @default.
- W4308562693 hasAuthorship W4308562693A5085619057 @default.
- W4308562693 hasConcept C121332964 @default.
- W4308562693 hasConcept C127413603 @default.
- W4308562693 hasConcept C130349721 @default.
- W4308562693 hasConcept C138631740 @default.
- W4308562693 hasConcept C145148216 @default.
- W4308562693 hasConcept C147789679 @default.
- W4308562693 hasConcept C163258240 @default.
- W4308562693 hasConcept C171250308 @default.
- W4308562693 hasConcept C17525397 @default.
- W4308562693 hasConcept C178790620 @default.
- W4308562693 hasConcept C185592680 @default.
- W4308562693 hasConcept C191897082 @default.
- W4308562693 hasConcept C192562407 @default.
- W4308562693 hasConcept C2776301907 @default.
- W4308562693 hasConcept C42360764 @default.
- W4308562693 hasConcept C52859227 @default.
- W4308562693 hasConcept C537181965 @default.
- W4308562693 hasConcept C69357855 @default.
- W4308562693 hasConcept C73916439 @default.
- W4308562693 hasConcept C89395315 @default.
- W4308562693 hasConcept C97355855 @default.
- W4308562693 hasConceptScore W4308562693C121332964 @default.