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- W4308639769 endingPage "15414" @default.
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- W4308639769 abstract "N-alkylation of amines is an important catalytic reaction in synthetic chemistry. Herein, we report a simple strategy for the N-alkylation of 2-aminopyridines with 1,2-diketones using BF3·OEt2 as a catalyst. The reaction proceeds under aerobic conditions, leading to the formation of a diverse range of substituted secondary amines in good to excellent yields. A close inspection of the mechanistic pathway using various spectroscopic techniques and the computational study revealed that the reaction proceeds through the formation of an iminium–keto intermediate with the liberation of CO2." @default.
- W4308639769 created "2022-11-13" @default.
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- W4308639769 date "2022-11-09" @default.
- W4308639769 modified "2023-10-14" @default.
- W4308639769 title "Catalytic and Mechanistic Approach to the Metal-Free N-Alkylation of 2-Aminopyridines with Diketones" @default.
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- W4308639769 doi "https://doi.org/10.1021/acs.joc.2c01957" @default.
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