Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308679570> ?p ?o ?g. }
- W4308679570 endingPage "51866" @default.
- W4308679570 startingPage "51855" @default.
- W4308679570 abstract "Metal nanoparticles grafted within inert and porous wide-area supports are emerging as recyclable, sustainable catalysts for modern industry applications. Here, we bioengineered gold nanoparticle-based supported catalysts by utilizing the innate metal binding and reductive potential of eggshell as a sustainable strategy. Variable hand-recyclable wide-area three-dimensional catalysts between ∼80 ± 7 and 0.5 ± 0.1 cm2 are generated simply by controlling the size of the support. The catalyst possessed high-temperature stability (300 °C) and compatibility toward polar and nonpolar solvents, electrolytes, acids, and bases facilitating ultra-efficient catalysis of accordingly suspended substrates. Validation was done by large-volume (2.8 liters) dye detoxification, gram-scale hydrogenation of nitroarene, and the synthesis of propargylamine. Moreover, persistent recyclability, monitoring of reaction kinetics, and product intermediates are possible due to physical retrievability and interchangeability of the catalyst. Finally, the bionature of the support permits ∼76.9 ± 8% recovery of noble gold simply by immersing in a royal solution. Our naturally created, low-cost, scalable, hand-recyclable, and resilient supported mega-catalyst dwarfs most challenges for large-scale metal-based heterogeneous catalysis." @default.
- W4308679570 created "2022-11-14" @default.
- W4308679570 creator A5006244527 @default.
- W4308679570 creator A5014175694 @default.
- W4308679570 creator A5016667019 @default.
- W4308679570 creator A5025243945 @default.
- W4308679570 creator A5032000485 @default.
- W4308679570 creator A5036037380 @default.
- W4308679570 creator A5041252482 @default.
- W4308679570 creator A5049811778 @default.
- W4308679570 creator A5052531952 @default.
- W4308679570 creator A5061902568 @default.
- W4308679570 creator A5083139226 @default.
- W4308679570 creator A5086714072 @default.
- W4308679570 date "2022-11-10" @default.
- W4308679570 modified "2023-10-16" @default.
- W4308679570 title "Sustainable Bioengineering of Gold Structured Wide-Area Supported Catalysts for Hand-Recyclable Ultra-Efficient Heterogeneous Catalysis" @default.
- W4308679570 cites W1753956108 @default.
- W4308679570 cites W1929821729 @default.
- W4308679570 cites W1976844151 @default.
- W4308679570 cites W1979221090 @default.
- W4308679570 cites W1998157539 @default.
- W4308679570 cites W1998358855 @default.
- W4308679570 cites W2000068330 @default.
- W4308679570 cites W2001222253 @default.
- W4308679570 cites W2008972212 @default.
- W4308679570 cites W2010060360 @default.
- W4308679570 cites W2019584170 @default.
- W4308679570 cites W2037016796 @default.
- W4308679570 cites W2054159142 @default.
- W4308679570 cites W2054719553 @default.
- W4308679570 cites W2064871488 @default.
- W4308679570 cites W2069569112 @default.
- W4308679570 cites W2076048962 @default.
- W4308679570 cites W2083675762 @default.
- W4308679570 cites W2086400678 @default.
- W4308679570 cites W2089681877 @default.
- W4308679570 cites W2099377634 @default.
- W4308679570 cites W2106125134 @default.
- W4308679570 cites W2107129115 @default.
- W4308679570 cites W2120798151 @default.
- W4308679570 cites W2314213609 @default.
- W4308679570 cites W2318845935 @default.
- W4308679570 cites W2320378008 @default.
- W4308679570 cites W2323772697 @default.
- W4308679570 cites W2329287320 @default.
- W4308679570 cites W2345910619 @default.
- W4308679570 cites W2426795413 @default.
- W4308679570 cites W2528976232 @default.
- W4308679570 cites W2532166291 @default.
- W4308679570 cites W2588782622 @default.
- W4308679570 cites W2792589001 @default.
- W4308679570 cites W2794616195 @default.
- W4308679570 cites W2794774894 @default.
- W4308679570 cites W2805499137 @default.
- W4308679570 cites W2887870870 @default.
- W4308679570 cites W2890836740 @default.
- W4308679570 cites W2903213280 @default.
- W4308679570 cites W2921880292 @default.
- W4308679570 cites W2944635422 @default.
- W4308679570 cites W2966914901 @default.
- W4308679570 cites W2969730862 @default.
- W4308679570 cites W2970385182 @default.
- W4308679570 cites W2995779806 @default.
- W4308679570 cites W3003118458 @default.
- W4308679570 cites W3003512739 @default.
- W4308679570 cites W3004713681 @default.
- W4308679570 cites W3006289439 @default.
- W4308679570 cites W3013754189 @default.
- W4308679570 cites W3017796938 @default.
- W4308679570 cites W3026153519 @default.
- W4308679570 cites W3035372044 @default.
- W4308679570 cites W3043702992 @default.
- W4308679570 cites W3044792591 @default.
- W4308679570 cites W3190172293 @default.
- W4308679570 cites W3200199054 @default.
- W4308679570 cites W4230143238 @default.
- W4308679570 doi "https://doi.org/10.1021/acsami.2c13564" @default.
- W4308679570 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36354751" @default.
- W4308679570 hasPublicationYear "2022" @default.
- W4308679570 type Work @default.
- W4308679570 citedByCount "1" @default.
- W4308679570 countsByYear W43086795702023 @default.
- W4308679570 crossrefType "journal-article" @default.
- W4308679570 hasAuthorship W4308679570A5006244527 @default.
- W4308679570 hasAuthorship W4308679570A5014175694 @default.
- W4308679570 hasAuthorship W4308679570A5016667019 @default.
- W4308679570 hasAuthorship W4308679570A5025243945 @default.
- W4308679570 hasAuthorship W4308679570A5032000485 @default.
- W4308679570 hasAuthorship W4308679570A5036037380 @default.
- W4308679570 hasAuthorship W4308679570A5041252482 @default.
- W4308679570 hasAuthorship W4308679570A5049811778 @default.
- W4308679570 hasAuthorship W4308679570A5052531952 @default.
- W4308679570 hasAuthorship W4308679570A5061902568 @default.
- W4308679570 hasAuthorship W4308679570A5083139226 @default.
- W4308679570 hasAuthorship W4308679570A5086714072 @default.
- W4308679570 hasConcept C127413603 @default.
- W4308679570 hasConcept C154256306 @default.