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- W4308683239 abstract "A novel methodology for the annulation of terminal alkynes and o-phenylenediamines by using a combination of a cobalt catalyst and oxygen as a terminal oxidant is reported. This method shows wide substrate scope and good functional group tolerance and provides a wide range of quinoxalines in good to high yields. The method is demonstrated by its gram-scale and broad potential applications. Furthermore, this protocol serves as a powerful tool for the late-stage functionalization of various complex bioactive molecules and drugs to provide a new class of molecules containing two distinct bioactive molecules directly linked. Detailed mechanistic studies reveal that the current reaction goes through a novel mechanism different from the previously reported glyoxal mechanism." @default.
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- W4308683239 date "2022-11-09" @default.
- W4308683239 modified "2023-09-28" @default.
- W4308683239 title "Cobalt-Catalyzed Effective Access to Quinoxalines with Insights in Annulation of Terminal Alkynes and <i>o</i>-Phenylenediamines" @default.
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- W4308683239 doi "https://doi.org/10.1021/acs.orglett.2c03465" @default.
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