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- W4308773245 abstract "The two-faced reactivity of N-allenamides allows regio- and stereo-controlled functionalization at the α-, β- and γ-positions of the nitrogen atom. The contingency to obtain either proximal or distal adducts makes these substrates essential for the construction of complex heterocyclic scaffolds. This review covers the recent advances made in the development of new methods involving amination and alkoxylation reactions on N-allenamides leading to a broad array of N-heterocycles. The syntheses reported herein are classified based on their reaction type. In addition, mechanistic perceptions are provided for the majority of the discussed transformations." @default.
- W4308773245 created "2022-11-15" @default.
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- W4308773245 date "2022-01-01" @default.
- W4308773245 modified "2023-09-30" @default.
- W4308773245 title "Construction of C–N and C–O bonds based on <i>N</i>-allenamide functionalization" @default.
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- W4308773245 doi "https://doi.org/10.1039/d2ob01768g" @default.
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