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- W4308808597 abstract "Reaction of excess 3-chloropyridine (3-Clpy) with tetrameric trimethylplatinum(IV) iodide [PtMe3I]4 afforded a mononuclear complex [PtMe3I(3-Clpy)2] (1). The complex 1 has been characterized by 1H NMR and elemental analysis. Further, 1H NMR spectrum of 1 in CDCl3 also shows the presence of a small amount of dinuclear complexes syn-[PtMe3I(3-Clpy)]2 (2) and anti-[PtMe3I(3-Clpy)]2 (3) along with free pyridine ligand. The complex 1 on treatment with [PtMe3I]4 forms syn and anti dinuclear complexes 2 and 3. The reaction has been studied by 1H NMR spectroscopy. The crystal structure of 2·[PtMe3I]4 has also been determined." @default.
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- W4308808597 date "2023-01-01" @default.
- W4308808597 modified "2023-09-28" @default.
- W4308808597 title "Synthesis, structure, and solution behavior of trimethylplatinum(IV) iodide complexes of 3-chloropyridine" @default.
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- W4308808597 doi "https://doi.org/10.1016/j.poly.2022.116201" @default.
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