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• W4308926136 abstract "Two quaternary hetero-transition metal sulfides RbAg 5 HgS 4 ( 1 ) and CsAgHgS 2 ( 2 ) have been successfully synthesized under mild solvothermal method in the presence of thiophenol as a mineralizer. Compound 1 features an interesting 3-D [Ag 5 HgS 4 ] - framework composed of 16-membered ring [Ag(2) 4 M(1) 4 S 8 ] (M = Ag/Hg) and quasi-8-membered ring [Ag(2) 4 S 4 ] which are all constructed by MS 2 and AgS 2 linear units. Compound 2 possesses anionic [AgHgS 2 ] n n− layers formed with MS 4 (M = Ag/Hg) tetrahedra, in which Ag + and Hg 2+ ions occupy the same crystallographic site. Particularly, this is the first time that quaternary A-Ag-Hg-S (A = alkali metal) system were explored via solvothermal method, which demonstrates that structural directing agents have significant influence on the structures of hetero-transition metal sulfides. Furthermore, the XRD experiment and band gap value of compound 2 were also investigated. Two quaternary hetero-transition metal sulfides RbAg 5 HgS 4 ( 1 ) and CsAgHgS 2 ( 2 ) have been successfully synthesized under mild solvothermal method in the presence of thiophenol as a mineralizer. Compound 1 features an interesting 3-D [Ag 5 HgS 4 ] - framework composed of 16-membered ring [Ag(2) 4 M(1) 4 S 8 ] (M = Ag/Hg) and quasi-8-membered ring [Ag(2) 4 S 4 ] which are all constructed by MS 2 and AgS 2 linear units. Compound 2 possesses anionic [AgHgS 2 ] n n− layers formed with MS 4 (M = Ag/Hg) tetrahedra, in which Ag + and Hg 2+ ions occupy the same crystallographic site. • Two quaternary hetero-transition metal sulfides RbAg 5 HgS 4 ( 1 ) and CsAgHgS 2 ( 2 ) were synthesized under solvothermal conditions using thiophenol as a mineralizer. • Compound 1 features an interesting 3-D [Ag 5 HgS 4 ] - framework composed of 16-membered ring [Ag (2) 4 M(1) 4 S 8 ] (M = Ag/Hg) and quasi-8-membered ring [Ag (2) 4 S 4 ] which are all constructed by MS 2 and AgS 2 linear units. • Compound 2 possesses anionic [AgHgS 2 ] n n− layers formed with MS 4 (M = Ag/Hg) tetrahedra. • The completely different structures of the two sulfides are due to the usage of different structural directing agents." @default.
• W4308926136 created "2022-11-19" @default.
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• W4308926136 date "2023-02-01" @default.
• W4308926136 modified "2023-10-05" @default.
• W4308926136 title "Mild solvothermal syntheses and crystal structures of two quaternary hetero-transition metal sulfides RbAg5HgS4 and CsAgHgS2" @default.
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• W4308926136 doi "https://doi.org/10.1016/j.jssc.2022.123716" @default.
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