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• W4308927958 endingPage "118284" @default.
• W4308927958 startingPage "118284" @default.
• W4308927958 abstract "Pressure–temperature phase diagram calculated using a novel VLAH four-phase equilibrium calculation algorithm for a H 2 O/CH 4 /C 2 H 6 /C 3 H 8 mixture with a molar ratio of 40:5:2:3. Specifications: V, vapor phase; L, hydrocarbon-rich liquid phase; A, aqueous phase; H, gas hydrate phase. • A multiphase equilibrium calculation algorithm for hydrate-forming systems. • A new criterion for determining the onset of hydrate dissociation. • Pressure-temperature and pressure-composition phase diagrams involving hydrates. • Reasonable predictions for phase fractions and phase compositions. In this study, we developed an algorithm for vapor–liquid–aqueous–hydrate four-phase equilibrium calculations. The algorithm was formulated in a stage-wise manner: a stability test was first conducted, followed by flash calculations if instability was determined. In addition to the van der Waals–Platteeuw model for predicting the presence of a hydrate phase, we propose a novel criterion for determining the onset of hydrate dissociation. To calculate phase fractions and compositions, our algorithm provides a series of material-balance equations for hydrates. Sample calculations were conducted for several fluids. For the sample fluids, the pressure–temperature and pressure–composition phase diagrams were plotted for systems containing the hydrate phase, using the developed four-phase equilibrium calculation algorithm to conduct point-to-point calculations, which demonstrated its robustness and accuracy." @default.
• W4308927958 created "2022-11-19" @default.
• W4308927958 creator A5028462736 @default.
• W4308927958 creator A5064925349 @default.
• W4308927958 date "2023-03-01" @default.
• W4308927958 modified "2023-09-23" @default.
• W4308927958 title "A novel four-phase equilibrium calculation algorithm for water/hydrocarbon systems containing gas hydrates" @default.
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• W4308927958 doi "https://doi.org/10.1016/j.ces.2022.118284" @default.
• W4308927958 hasPublicationYear "2023" @default.
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