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• W4308952580 abstract "An aryl disulfide mediated C–F bond activation of the trifluoromethyl group to generate valuable gem-difluoroalkylindoles is described. This method relies on readily available commodity reagents under mild reaction conditions and represents the first transition-metal-free redox-neutral C–F bond activation strategy. The reaction employs various substituted indoles and α-fluoro-substituted esters. Further, this mode of C–F activation was also amenable to the activation of trifluoromethylated arenes for the preparation of bis-benzylic gem-difluoromethylenes between indole and arene substructures, providing access to a unique chemical space." @default.
• W4308952580 created "2022-11-20" @default.
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• W4308952580 date "2022-11-14" @default.
• W4308952580 modified "2023-10-15" @default.
• W4308952580 title "Visible-Light-Induced C–F Bond Activation for the Difluoroalkylation of Indoles" @default.
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• W4308952580 doi "https://doi.org/10.1021/acs.orglett.2c03549" @default.
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