Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308957041> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W4308957041 endingPage "10770" @default.
- W4308957041 startingPage "10767" @default.
- W4308957041 abstract "Employing metal–organic frameworks (MOFs) as water adsorbents has become a flourishing field in recent years. Aluminum isophthalate [Al(OH)(bdc)]·nH2O, referred to as CAU-10-H, is renowned for its high physical and chemical stability under external mechanical stimuli, which is crucial for use in sorption-based heat exchange. We report pressure-induced structural changes and water uptake/release of CAU-10-H in the gigapascal regime. CAU-10-H displays four different phases during pressurization in water up to 4.08(1) GPa. Upon immersion in water at ambient conditions, the unit cell volume expands by 1.3(1)%, by increasing water content from 78.7(1) to 85.6(1) H2O per unit cell. Upon pressurization to 1.08(1) GPa, the water content increases gradually to 112.5(1) H2O per unit cell and reduces the symmetry to P1 phase. At 1.72(1) GPa, a correlated “gate-opening/channel-closing” transition to a centrosymmetric Pnma phase occurs to increase the unit cell volume by 6.9(1)% and water content to 138.8(1) H2O per unit cell. Further increase in pressure to 4.08(1) GPa then leads to a gradual decrease in water content to 119.2(1) H2O per unit cell and redistribution of the inserted water molecules during a “gate-closing/channel-opening” transition to an I41/amd phase. After pressure removal, CAU-10-H reverts to its initial state in terms of crystallinity and water content. This pressure-induced water adsorption/desorption and concerted movements of gate-constraining ligands provides a detailed understanding of the water-MOF interplay, which can be used as a basis for designing new materials, possibly utilizing pressure as a tool for chemical modifications." @default.
- W4308957041 created "2022-11-20" @default.
- W4308957041 creator A5030649976 @default.
- W4308957041 creator A5045762699 @default.
- W4308957041 creator A5049289942 @default.
- W4308957041 date "2022-11-14" @default.
- W4308957041 modified "2023-09-27" @default.
- W4308957041 title "Structuration of Water in Microporous CAU-10-H under Gigapascal Pressure" @default.
- W4308957041 cites W1994839037 @default.
- W4308957041 cites W1999908724 @default.
- W4308957041 cites W2013556140 @default.
- W4308957041 cites W2021523927 @default.
- W4308957041 cites W2037112113 @default.
- W4308957041 cites W2043309554 @default.
- W4308957041 cites W2112823952 @default.
- W4308957041 cites W2141939342 @default.
- W4308957041 cites W2142699453 @default.
- W4308957041 cites W2254837646 @default.
- W4308957041 cites W2466286502 @default.
- W4308957041 cites W2885470277 @default.
- W4308957041 doi "https://doi.org/10.1021/acs.jpclett.2c02729" @default.
- W4308957041 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36374519" @default.
- W4308957041 hasPublicationYear "2022" @default.
- W4308957041 type Work @default.
- W4308957041 citedByCount "1" @default.
- W4308957041 countsByYear W43089570412022 @default.
- W4308957041 crossrefType "journal-article" @default.
- W4308957041 hasAuthorship W4308957041A5030649976 @default.
- W4308957041 hasAuthorship W4308957041A5045762699 @default.
- W4308957041 hasAuthorship W4308957041A5049289942 @default.
- W4308957041 hasConcept C113196181 @default.
- W4308957041 hasConcept C121332964 @default.
- W4308957041 hasConcept C127413603 @default.
- W4308957041 hasConcept C149288129 @default.
- W4308957041 hasConcept C150394285 @default.
- W4308957041 hasConcept C178790620 @default.
- W4308957041 hasConcept C185592680 @default.
- W4308957041 hasConcept C192562407 @default.
- W4308957041 hasConcept C42360764 @default.
- W4308957041 hasConcept C46275449 @default.
- W4308957041 hasConcept C58445606 @default.
- W4308957041 hasConcept C8010536 @default.
- W4308957041 hasConcept C86381522 @default.
- W4308957041 hasConcept C97355855 @default.
- W4308957041 hasConceptScore W4308957041C113196181 @default.
- W4308957041 hasConceptScore W4308957041C121332964 @default.
- W4308957041 hasConceptScore W4308957041C127413603 @default.
- W4308957041 hasConceptScore W4308957041C149288129 @default.
- W4308957041 hasConceptScore W4308957041C150394285 @default.
- W4308957041 hasConceptScore W4308957041C178790620 @default.
- W4308957041 hasConceptScore W4308957041C185592680 @default.
- W4308957041 hasConceptScore W4308957041C192562407 @default.
- W4308957041 hasConceptScore W4308957041C42360764 @default.
- W4308957041 hasConceptScore W4308957041C46275449 @default.
- W4308957041 hasConceptScore W4308957041C58445606 @default.
- W4308957041 hasConceptScore W4308957041C8010536 @default.
- W4308957041 hasConceptScore W4308957041C86381522 @default.
- W4308957041 hasConceptScore W4308957041C97355855 @default.
- W4308957041 hasFunder F4320322030 @default.
- W4308957041 hasIssue "46" @default.
- W4308957041 hasLocation W43089570411 @default.
- W4308957041 hasLocation W43089570412 @default.
- W4308957041 hasOpenAccess W4308957041 @default.
- W4308957041 hasPrimaryLocation W43089570411 @default.
- W4308957041 hasRelatedWork W2068953041 @default.
- W4308957041 hasRelatedWork W2076257538 @default.
- W4308957041 hasRelatedWork W2158251285 @default.
- W4308957041 hasRelatedWork W2369102758 @default.
- W4308957041 hasRelatedWork W2401134095 @default.
- W4308957041 hasRelatedWork W2548638064 @default.
- W4308957041 hasRelatedWork W2948745210 @default.
- W4308957041 hasRelatedWork W3008509564 @default.
- W4308957041 hasRelatedWork W4223459795 @default.
- W4308957041 hasRelatedWork W4224436599 @default.
- W4308957041 hasVolume "13" @default.
- W4308957041 isParatext "false" @default.
- W4308957041 isRetracted "false" @default.
- W4308957041 workType "article" @default.