Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308987285> ?p ?o ?g. }
- W4308987285 endingPage "102958" @default.
- W4308987285 startingPage "102958" @default.
- W4308987285 abstract "It was six transition metal magnetic catalysts (TMMC) of Fe3O4, La/Fe3O4, Cs/Fe3O4, Mn/Fe3O4, Ce/Fe3O4 and Pd/Fe3O4 that on the catalytic oxidation phosphine (PH3) were researched in external magnetic field (MF). It was found that transition metal (TM) and MF had significant effect on improving PH3 removal, where the Mn/Fe3O4 was the best TMMC for the catalytic oxidation PH3. When the Mn/Fe3O4:H2O was 1.5:5.0, reaction temperature was 50 °C, O2 content was 5% as well as the MF strength was 10.0 A, the PH3 purification efficiency could be up to 82.84% and last for 7 h. In addition, it was transmission electron microscope (TEM), Raman spectroscopy (RS) and comsol multiphysics (CM) that were applied to characterize and analyze the mechanism on liquid phase catalytic oxidation PH3, of which the MF strengthening effects were mainly divided into physical and chemical effects. The physical effects were that the particles were moved in the same direction by the MF, which made the catalysts contact with PH3 and O2 more homogeneous so as to improve the PH3 removal efficiency. While the chemical effect was that the chemical adsorption of PH3 and O2 was promoted by MF firstly on the surface of the particles under the action of Faraday force. Then the reaction of PH3 catalytic oxidation was promoted by TMMC. When the TMMC was magnetized by MF, the effect of Me2+/Fe3+/Fe2+ ions was further enhanced and finally the catalytic oxidation reaction of PH3 was further enhanced, which provided the direction for quickly harmless of PH3." @default.
- W4308987285 created "2022-11-20" @default.
- W4308987285 creator A5010712606 @default.
- W4308987285 creator A5036984014 @default.
- W4308987285 creator A5043008166 @default.
- W4308987285 creator A5050476988 @default.
- W4308987285 creator A5050808398 @default.
- W4308987285 creator A5070011694 @default.
- W4308987285 creator A5080782626 @default.
- W4308987285 creator A5085842719 @default.
- W4308987285 date "2022-11-01" @default.
- W4308987285 modified "2023-10-09" @default.
- W4308987285 title "The mechanism of catalytic oxidation phosphine in liquid phase by transition metal magnetic catalyst in external magnetic field" @default.
- W4308987285 cites W1965420484 @default.
- W4308987285 cites W1973626287 @default.
- W4308987285 cites W1974925147 @default.
- W4308987285 cites W1978064474 @default.
- W4308987285 cites W1983941923 @default.
- W4308987285 cites W1986377130 @default.
- W4308987285 cites W1986510254 @default.
- W4308987285 cites W1991633856 @default.
- W4308987285 cites W2033007989 @default.
- W4308987285 cites W2048147320 @default.
- W4308987285 cites W2072698541 @default.
- W4308987285 cites W2077414565 @default.
- W4308987285 cites W2086119339 @default.
- W4308987285 cites W2118736378 @default.
- W4308987285 cites W2200148653 @default.
- W4308987285 cites W2326133623 @default.
- W4308987285 cites W2332634510 @default.
- W4308987285 cites W2345424636 @default.
- W4308987285 cites W2464773599 @default.
- W4308987285 cites W2531669580 @default.
- W4308987285 cites W2532216349 @default.
- W4308987285 cites W2582656969 @default.
- W4308987285 cites W2755625903 @default.
- W4308987285 cites W2761367290 @default.
- W4308987285 cites W2767932297 @default.
- W4308987285 cites W2768085506 @default.
- W4308987285 cites W2789601655 @default.
- W4308987285 cites W2794739407 @default.
- W4308987285 cites W2804228280 @default.
- W4308987285 cites W2967570969 @default.
- W4308987285 cites W2991178750 @default.
- W4308987285 cites W3001202973 @default.
- W4308987285 cites W3007834764 @default.
- W4308987285 cites W3015361696 @default.
- W4308987285 cites W3036092899 @default.
- W4308987285 cites W3043281622 @default.
- W4308987285 cites W3159609931 @default.
- W4308987285 cites W3178492384 @default.
- W4308987285 cites W3187676053 @default.
- W4308987285 doi "https://doi.org/10.1016/j.eti.2022.102958" @default.
- W4308987285 hasPublicationYear "2022" @default.
- W4308987285 type Work @default.
- W4308987285 citedByCount "0" @default.
- W4308987285 crossrefType "journal-article" @default.
- W4308987285 hasAuthorship W4308987285A5010712606 @default.
- W4308987285 hasAuthorship W4308987285A5036984014 @default.
- W4308987285 hasAuthorship W4308987285A5043008166 @default.
- W4308987285 hasAuthorship W4308987285A5050476988 @default.
- W4308987285 hasAuthorship W4308987285A5050808398 @default.
- W4308987285 hasAuthorship W4308987285A5070011694 @default.
- W4308987285 hasAuthorship W4308987285A5080782626 @default.
- W4308987285 hasAuthorship W4308987285A5085842719 @default.
- W4308987285 hasBestOaLocation W43089872851 @default.
- W4308987285 hasConcept C106773901 @default.
- W4308987285 hasConcept C113196181 @default.
- W4308987285 hasConcept C127413603 @default.
- W4308987285 hasConcept C147789679 @default.
- W4308987285 hasConcept C150394285 @default.
- W4308987285 hasConcept C161790260 @default.
- W4308987285 hasConcept C178790620 @default.
- W4308987285 hasConcept C179104552 @default.
- W4308987285 hasConcept C185592680 @default.
- W4308987285 hasConcept C192562407 @default.
- W4308987285 hasConcept C2777716191 @default.
- W4308987285 hasConcept C42360764 @default.
- W4308987285 hasConcept C43617362 @default.
- W4308987285 hasConcept C544153396 @default.
- W4308987285 hasConcept C77176794 @default.
- W4308987285 hasConcept C78030364 @default.
- W4308987285 hasConceptScore W4308987285C106773901 @default.
- W4308987285 hasConceptScore W4308987285C113196181 @default.
- W4308987285 hasConceptScore W4308987285C127413603 @default.
- W4308987285 hasConceptScore W4308987285C147789679 @default.
- W4308987285 hasConceptScore W4308987285C150394285 @default.
- W4308987285 hasConceptScore W4308987285C161790260 @default.
- W4308987285 hasConceptScore W4308987285C178790620 @default.
- W4308987285 hasConceptScore W4308987285C179104552 @default.
- W4308987285 hasConceptScore W4308987285C185592680 @default.
- W4308987285 hasConceptScore W4308987285C192562407 @default.
- W4308987285 hasConceptScore W4308987285C2777716191 @default.
- W4308987285 hasConceptScore W4308987285C42360764 @default.
- W4308987285 hasConceptScore W4308987285C43617362 @default.
- W4308987285 hasConceptScore W4308987285C544153396 @default.
- W4308987285 hasConceptScore W4308987285C77176794 @default.
- W4308987285 hasConceptScore W4308987285C78030364 @default.