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- W4309046951 abstract "Flexible zinc-ion batteries (ZIBs) are promising power sources for portable devices due to their high safety and low production cost. However, the low mass-loading and limited areal capacity of cathode materials are the major problems blocking the practicability of ZIBs. Herein, a high mass-loading and binder-free flexible vanadium oxide (MCV@CC) cathode with a large areal capacity was fabricated via the bridge effect of MXene. The functional MXene bridge induces the growth of the vanadium oxide active layer on the carbon cloth (CC) flexible substrate. The binder-free cathode can reduce the electrochemically inactive weight of the whole electrode, which enhances the energy density of ZIBs. Consequently, the MCV@CC cathode (mass-loading of ∼7 mg cm−2) delivers a desirable areal capacity (2.36 mAh cm−2) and good cycling stability (capacity retention of 86.1% after 1200 cycles at 10 mA cm−2). Moreover, several ex-situ characterization results indicate that the reaction mechanism upon battery cycling is based on the reversible Zn2+/H+ (de)intercalation in the vanadium oxide interlayer. Furthermore, the assembled quasi-solid-state MCV@CC//Zn flexible battery exhibits decent performance at different bending states. Such a bridge effect strategy sheds light on the construction of high mass-loading flexible electrodes for ZIBs applications." @default.
- W4309046951 created "2022-11-21" @default.
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- W4309046951 date "2023-04-01" @default.
- W4309046951 modified "2023-10-18" @default.
- W4309046951 title "High mass-loading and binder-free flexible vanadium-based oxide cathode for zinc-ion battery via a bridge of MXene" @default.
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- W4309046951 doi "https://doi.org/10.1016/j.jmst.2022.09.042" @default.
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