Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309046977> ?p ?o ?g. }
- W4309046977 abstract "Abstract The harvesting of ‘hot’ triplet excitons through high-lying reverse intersystem crossing mechanism has emerged as a hot research issue in the field of organic light-emitting diodes. However, if high-lying reverse intersystem crossing materials lack the capability to convert ‘cold’ T 1 excitons into singlet ones, the actual maximum exciton utilization efficiency would generally deviate from 100%. Herein, through comparative studies on two naphthalimide-based compounds CzNI and TPANI, we revealed that the ‘cold’ T 1 excitons in high-lying reverse intersystem crossing materials can be utilized effectively through the triplet-triplet annihilation- mediated high-lying reverse intersystem crossing process if they possess certain triplet-triplet upconversion capability. Especially, quite effective triplet-triplet annihilation- mediated high-lying reverse intersystem crossing can be triggered by endowing the high-lying reverse intersystem crossing process with a 3 ππ*→ 1 nπ* character. By taking advantage of the permanent orthogonal orbital transition effect of 3 ππ*→ 1 nπ*, spin–orbit coupling matrix elements of ca. 10 cm −1 can be acquired, and hence ultra-fast mediated high-lying reverse intersystem crossing process with rate constant over 10 9 s −1 can be realized." @default.
- W4309046977 created "2022-11-21" @default.
- W4309046977 creator A5001201295 @default.
- W4309046977 creator A5003850660 @default.
- W4309046977 creator A5005296833 @default.
- W4309046977 creator A5016574602 @default.
- W4309046977 creator A5019038052 @default.
- W4309046977 creator A5037422169 @default.
- W4309046977 creator A5037593812 @default.
- W4309046977 creator A5038857235 @default.
- W4309046977 creator A5039449480 @default.
- W4309046977 creator A5039693533 @default.
- W4309046977 creator A5048997362 @default.
- W4309046977 creator A5049229521 @default.
- W4309046977 creator A5053958450 @default.
- W4309046977 creator A5063532061 @default.
- W4309046977 creator A5091162630 @default.
- W4309046977 date "2022-11-12" @default.
- W4309046977 modified "2023-09-30" @default.
- W4309046977 title "Ultra-fast triplet-triplet-annihilation-mediated high-lying reverse intersystem crossing triggered by participation of nπ*-featured excited states" @default.
- W4309046977 cites W1823915597 @default.
- W4309046977 cites W1886596767 @default.
- W4309046977 cites W1979214388 @default.
- W4309046977 cites W1987164427 @default.
- W4309046977 cites W1992766461 @default.
- W4309046977 cites W2015554500 @default.
- W4309046977 cites W2064439266 @default.
- W4309046977 cites W2064982445 @default.
- W4309046977 cites W2068539433 @default.
- W4309046977 cites W2085244076 @default.
- W4309046977 cites W2094391871 @default.
- W4309046977 cites W2095024481 @default.
- W4309046977 cites W2152047537 @default.
- W4309046977 cites W2152816112 @default.
- W4309046977 cites W2275659144 @default.
- W4309046977 cites W2317123838 @default.
- W4309046977 cites W2404483643 @default.
- W4309046977 cites W2592066197 @default.
- W4309046977 cites W2599692897 @default.
- W4309046977 cites W2599910703 @default.
- W4309046977 cites W2646964508 @default.
- W4309046977 cites W2769010979 @default.
- W4309046977 cites W2791030457 @default.
- W4309046977 cites W2899833003 @default.
- W4309046977 cites W2900296960 @default.
- W4309046977 cites W2944212635 @default.
- W4309046977 cites W2951817187 @default.
- W4309046977 cites W2977637530 @default.
- W4309046977 cites W2980676830 @default.
- W4309046977 cites W2991198080 @default.
- W4309046977 cites W2996960967 @default.
- W4309046977 cites W3001004385 @default.
- W4309046977 cites W3022712662 @default.
- W4309046977 cites W3023721724 @default.
- W4309046977 cites W3036344691 @default.
- W4309046977 cites W3038997287 @default.
- W4309046977 cites W3102818580 @default.
- W4309046977 cites W3107656689 @default.
- W4309046977 cites W3117704281 @default.
- W4309046977 cites W3128701246 @default.
- W4309046977 cites W3159615978 @default.
- W4309046977 cites W3172021433 @default.
- W4309046977 cites W3183151438 @default.
- W4309046977 cites W3188436175 @default.
- W4309046977 cites W3192748980 @default.
- W4309046977 cites W3195059219 @default.
- W4309046977 cites W3198650202 @default.
- W4309046977 cites W3202293019 @default.
- W4309046977 cites W3205331515 @default.
- W4309046977 cites W3205497733 @default.
- W4309046977 cites W3210325891 @default.
- W4309046977 cites W3212593682 @default.
- W4309046977 cites W4206436693 @default.
- W4309046977 cites W4206526060 @default.
- W4309046977 cites W4210628676 @default.
- W4309046977 cites W4212824137 @default.
- W4309046977 cites W4225117300 @default.
- W4309046977 cites W4225372518 @default.
- W4309046977 cites W4285261736 @default.
- W4309046977 doi "https://doi.org/10.1038/s41467-022-34573-2" @default.
- W4309046977 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36371489" @default.
- W4309046977 hasPublicationYear "2022" @default.
- W4309046977 type Work @default.
- W4309046977 citedByCount "7" @default.
- W4309046977 countsByYear W43090469772023 @default.
- W4309046977 crossrefType "journal-article" @default.
- W4309046977 hasAuthorship W4309046977A5001201295 @default.
- W4309046977 hasAuthorship W4309046977A5003850660 @default.
- W4309046977 hasAuthorship W4309046977A5005296833 @default.
- W4309046977 hasAuthorship W4309046977A5016574602 @default.
- W4309046977 hasAuthorship W4309046977A5019038052 @default.
- W4309046977 hasAuthorship W4309046977A5037422169 @default.
- W4309046977 hasAuthorship W4309046977A5037593812 @default.
- W4309046977 hasAuthorship W4309046977A5038857235 @default.
- W4309046977 hasAuthorship W4309046977A5039449480 @default.
- W4309046977 hasAuthorship W4309046977A5039693533 @default.
- W4309046977 hasAuthorship W4309046977A5048997362 @default.
- W4309046977 hasAuthorship W4309046977A5049229521 @default.
- W4309046977 hasAuthorship W4309046977A5053958450 @default.
- W4309046977 hasAuthorship W4309046977A5063532061 @default.