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- W4309078434 abstract "Selective C–H bond functionalization of pyridine as a methodology for building complex molecules is of importance in all branches of chemical science. Compared with a more common C–H transformation at the ortho-position, lack of directing groups and electronic stabilization renders remote para-C–H activation of pyridine less accessible. The Ong and Nakao/Hiyama groups independently discovered a catalytic system based on cooperative Ni–Al to achieve para-selective alkenylation/alkylation of pyridine (Scheme A). These works, accompanied by solid-state structural evidence, establish a new platform in selective C–H catalysis based on a cooperative Ni–Al strategy." @default.
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- W4309078434 date "2023-03-01" @default.
- W4309078434 modified "2023-10-18" @default.
- W4309078434 title "Selective C–H activation of pyridine via Ni–Al" @default.
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- W4309078434 doi "https://doi.org/10.1016/j.trechm.2022.10.004" @default.
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