Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309079917> ?p ?o ?g. }
- W4309079917 endingPage "140002" @default.
- W4309079917 startingPage "140002" @default.
- W4309079917 abstract "• The hierarchical surface reactivity of CTOC was used to produce CTOC-Ars. • The conductivity and work function of CTOC-Ars films were improved. • CTOC-Ars can be general excellent CIL for efficient non-fullerene OSCs. • The improved interaction between TOC film and both donor and acceptor was unveiled. In this work, the hierarchical surface reactivity of a kind of Ti-oxo cluster (TOC) with robust cyclic structure, CTOC , supported by multiple surface ligands, has been initially established. By this method, a series of aromatics (i.e., benzoate for CTOC-Ph , 4-methylbenzoate for CTOC-PhMe and 4-cyanobenzoate for CTOC-PhCN ) substituted CTOC-Ars , with identical TOC core have been produced. These CTOC-Ars can be solution-processed into smooth films with order microstructures and optimized semiconducting properties, driven by intermolecular interactions of the aromatics. When using CTOC-Ph as cathode interlayer (CIL) in PM6:BO-4Cl based organic solar cells (OSCs), power conversion efficiencies (PCEs) up to 17.7 % have been achieved, much higher than 15.6 % of those with CTOC CIL. The distinct electron doping behavior with non-fullerene acceptor and higher adsorption energy with the polymer donor has been successfully unraveled, which can enable CTOC-Ph more intimate contact with the photoactive layer and facilitate more efficient charge transport. Moreover, the generality of CTOC-Ars as CIL for efficient OSCs has been confirmed in varied OSC systems, in which high PCEs of 18.4 % can be provided for PM6:L8-BO system." @default.
- W4309079917 created "2022-11-21" @default.
- W4309079917 creator A5001257595 @default.
- W4309079917 creator A5004909625 @default.
- W4309079917 creator A5005859878 @default.
- W4309079917 creator A5021761346 @default.
- W4309079917 creator A5049407947 @default.
- W4309079917 creator A5060968548 @default.
- W4309079917 creator A5072177258 @default.
- W4309079917 creator A5077323251 @default.
- W4309079917 creator A5080792359 @default.
- W4309079917 creator A5089082346 @default.
- W4309079917 date "2023-02-01" @default.
- W4309079917 modified "2023-10-18" @default.
- W4309079917 title "Surface tailored Ti-oxo clusters enabling highly efficient organic solar cells" @default.
- W4309079917 cites W1922922125 @default.
- W4309079917 cites W1938966388 @default.
- W4309079917 cites W2032813760 @default.
- W4309079917 cites W2033319706 @default.
- W4309079917 cites W2034743675 @default.
- W4309079917 cites W2046143366 @default.
- W4309079917 cites W2054810869 @default.
- W4309079917 cites W2120478834 @default.
- W4309079917 cites W2255871307 @default.
- W4309079917 cites W2270253191 @default.
- W4309079917 cites W2295691216 @default.
- W4309079917 cites W2356997838 @default.
- W4309079917 cites W2515158823 @default.
- W4309079917 cites W2560638817 @default.
- W4309079917 cites W2615203216 @default.
- W4309079917 cites W2615509149 @default.
- W4309079917 cites W2621472226 @default.
- W4309079917 cites W2766056672 @default.
- W4309079917 cites W2770965322 @default.
- W4309079917 cites W2771397493 @default.
- W4309079917 cites W2792920788 @default.
- W4309079917 cites W2831738429 @default.
- W4309079917 cites W2909990379 @default.
- W4309079917 cites W2954778364 @default.
- W4309079917 cites W2963243278 @default.
- W4309079917 cites W2978567597 @default.
- W4309079917 cites W2984973284 @default.
- W4309079917 cites W2994111815 @default.
- W4309079917 cites W3013756521 @default.
- W4309079917 cites W3023270715 @default.
- W4309079917 cites W3028938884 @default.
- W4309079917 cites W3045930519 @default.
- W4309079917 cites W3048385444 @default.
- W4309079917 cites W3089150264 @default.
- W4309079917 cites W3096205809 @default.
- W4309079917 cites W3107399537 @default.
- W4309079917 cites W3113354516 @default.
- W4309079917 cites W3124939073 @default.
- W4309079917 cites W3131292640 @default.
- W4309079917 cites W3142448629 @default.
- W4309079917 cites W3157813108 @default.
- W4309079917 cites W3161611462 @default.
- W4309079917 cites W3180126878 @default.
- W4309079917 cites W3186211058 @default.
- W4309079917 cites W4200514288 @default.
- W4309079917 cites W4207028762 @default.
- W4309079917 cites W4213245659 @default.
- W4309079917 cites W4220987085 @default.
- W4309079917 cites W4224025374 @default.
- W4309079917 cites W4224660088 @default.
- W4309079917 cites W4224981896 @default.
- W4309079917 cites W4226070796 @default.
- W4309079917 cites W4229013424 @default.
- W4309079917 cites W4233802867 @default.
- W4309079917 cites W4238123645 @default.
- W4309079917 cites W4250206343 @default.
- W4309079917 cites W4281569656 @default.
- W4309079917 cites W4286252291 @default.
- W4309079917 doi "https://doi.org/10.1016/j.cej.2022.140002" @default.
- W4309079917 hasPublicationYear "2023" @default.
- W4309079917 type Work @default.
- W4309079917 citedByCount "2" @default.
- W4309079917 countsByYear W43090799172023 @default.
- W4309079917 crossrefType "journal-article" @default.
- W4309079917 hasAuthorship W4309079917A5001257595 @default.
- W4309079917 hasAuthorship W4309079917A5004909625 @default.
- W4309079917 hasAuthorship W4309079917A5005859878 @default.
- W4309079917 hasAuthorship W4309079917A5021761346 @default.
- W4309079917 hasAuthorship W4309079917A5049407947 @default.
- W4309079917 hasAuthorship W4309079917A5060968548 @default.
- W4309079917 hasAuthorship W4309079917A5072177258 @default.
- W4309079917 hasAuthorship W4309079917A5077323251 @default.
- W4309079917 hasAuthorship W4309079917A5080792359 @default.
- W4309079917 hasAuthorship W4309079917A5089082346 @default.
- W4309079917 hasConcept C127413603 @default.
- W4309079917 hasConcept C159985019 @default.
- W4309079917 hasConcept C171250308 @default.
- W4309079917 hasConcept C185592680 @default.
- W4309079917 hasConcept C192562407 @default.
- W4309079917 hasConcept C2524010 @default.
- W4309079917 hasConcept C2776799497 @default.
- W4309079917 hasConcept C33923547 @default.
- W4309079917 hasConcept C39432304 @default.