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- W4309087078 abstract "Abstract In many metalloenzymes, sulfur‐containing ligands participate in catalytic processes, mainly via the involvement in electron transfer reactions. In a biomimetic approach, we now demonstrate the implication of S‐ligation in cobalt mediated oxygen reduction reactions (ORR). A comparative study between the catalytic ORR capabilities of the four‐nitrogen bound [Co(cyclam)] 2+ ( 1 ; cyclam=1,5,8,11‐tetraaza‐cyclotetradecane) and the S‐containing analog [Co(S 2 N 2 ‐cyclam)] 2+ ( 2 ; S 2 N 2 ‐cyclam=1,8‐dithia‐5,11‐diaza‐cyclotetradecane) reveals improved catalytic performance once the chalcogen is introduced in the Co coordination sphere. Trapping and characterization of the intermediates formed upon dioxygen activation at the Co II centers in 1 and 2 point to the involvement of sulfur in the O 2 reduction process as the key for the improved catalytic ORR capabilities of 2 ." @default.
- W4309087078 created "2022-11-21" @default.
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- W4309087078 date "2022-12-29" @default.
- W4309087078 modified "2023-10-18" @default.
- W4309087078 title "Evidence of Sulfur Non‐Innocence in [Co<sup>II</sup>(dithiacyclam)]<sup>2+</sup>‐Mediated Catalytic Oxygen Reduction Reactions" @default.
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- W4309087078 doi "https://doi.org/10.1002/anie.202214074" @default.
- W4309087078 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36378951" @default.
- W4309087078 hasPublicationYear "2022" @default.
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