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• W4309089105 abstract "Lanthanides are important fission products in molten salt reactors, and understanding their structure and that of their mixtures is relevant to many scientific and technological problems including the recovery and separation of rare earth elements using molten salt electrolysis. The literature on molten salts and specifically on LaCl3 and LaCl3-NaCl mixtures is often fragmented, with different experiments and simulations coinciding in their explanation for certain structural results but contradicting or questioning for others. Given the very practical importance that actinide and lanthanide salts have for energy applications, it is imperative to arrive at a clear unified picture of their local and intermediate-range structure in the neat molten state and when mixed with other salts. This article aims to unequivocally answer a set of specific questions: is it correct to think of long-lived octahedral coordination structures for La3+? What is the nature as a function of temperature of networks and intermediate-range order particularly upon dilution of the trivalent ion salt? Is the so-called scattering first sharp diffraction peak (FSDP) for neat LaCl3 truly indicative of intermediate-range order? If so, why is there a new lower-q peak when mixed with NaCl? Are X-ray scattering and Raman spectroscopy results fully consistent and easily described by simulation results? We will show that answers to these questions require that we abandon the idea of a most prominent coordination state for M3+ ions and instead think of multiple competing coordination states in exchange due to significant thermal energy in the molten state." @default.
• W4309089105 created "2022-11-21" @default.
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• W4309089105 date "2022-11-15" @default.
• W4309089105 modified "2023-10-16" @default.
• W4309089105 title "Complete Description of the LaCl₃–NaCl Melt Structure and the Concept of a Spacer Salt That Causes Structural Heterogeneity" @default.
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• W4309089105 cites W1903080689 @default.
• W4309089105 cites W1973408012 @default.
• W4309089105 cites W1973980277 @default.
• W4309089105 cites W1974619190 @default.
• W4309089105 cites W1974930704 @default.
• W4309089105 cites W1976120683 @default.
• W4309089105 cites W1984512160 @default.
• W4309089105 cites W1988048427 @default.
• W4309089105 cites W1993561200 @default.
• W4309089105 cites W1994614396 @default.
• W4309089105 cites W1995027 @default.
• W4309089105 cites W1996349416 @default.
• W4309089105 cites W1997724015 @default.
• W4309089105 cites W2003810177 @default.
• W4309089105 cites W2005878780 @default.
• W4309089105 cites W2006604766 @default.
• W4309089105 cites W2012780103 @default.
• W4309089105 cites W2017221680 @default.
• W4309089105 cites W2017747065 @default.
• W4309089105 cites W2032340699 @default.
• W4309089105 cites W2037758757 @default.
• W4309089105 cites W2044113944 @default.
• W4309089105 cites W2044567650 @default.
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• W4309089105 cites W2065912558 @default.
• W4309089105 cites W2066705112 @default.
• W4309089105 cites W2067039513 @default.
• W4309089105 cites W2067398693 @default.
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• W4309089105 cites W2071294982 @default.
• W4309089105 cites W2082500650 @default.
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• W4309089105 cites W2167590372 @default.
• W4309089105 cites W2280877349 @default.
• W4309089105 cites W2289882617 @default.
• W4309089105 cites W2310435753 @default.
• W4309089105 cites W2312644866 @default.
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• W4309089105 cites W2947137110 @default.
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• W4309089105 doi "https://doi.org/10.1021/jacs.2c09987" @default.
• W4309089105 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36379028" @default.
• W4309089105 hasPublicationYear "2022" @default.
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