Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309090180> ?p ?o ?g. }
- W4309090180 endingPage "1342" @default.
- W4309090180 startingPage "1342" @default.
- W4309090180 abstract "In this study, four monolithic, vanadium-based catalysts in granular (Vox/TiO2), honeycomb-type (Vox-Wox/TiO2 and Vox-MoOx/TiO2), and corrugated forms (Vox-Wox/TiO2) were investigated by multiple characterization methods (BET, XRF, XPS, XRD, H2-TPR, and NH3-TPD). Their catalytic performances were evaluated by the oxidation-reduction performance of ortho-dichlorobenzene (o-DCB) and NO/NH3. The modification of Wox and MoOx could promote catalytic activity by accelerating the transformation of V5+/V4+ and enriching the strong acid sites. The introduction of NO/NH3 significantly impaired the o-DCB oxidation, ascribed to the competitive adsorption of reactants on acid sites. The performance of Vox/TiO2 and Vox-MoOx/TiO2 catalysts indicated that strong acidity could enhance catalytic abilities over o-DCB and Nox. Nevertheless, the CE (conversion efficiency) of o-DCB was more related to a large BET surface area and a high amount of V5+ species, while the CE of Nox was more associated with redox ability and Vox surface density. The V4+/V5+ and OS-A/OS-L ratio increased prominently after the oxidation of o-DCB, indicating that it was the reoxidation of V4+ species, rather than the supplement of oxygen, that limited the reaction rate. This work revealed catalytic activity was positively affiliated with the surface area, amount of V5+ species, transformation rate of V4+/V5+, redox ability, and abundance of strong acid sites. Additionally, the results could guide the selectivity and improvement of industrial low-temperature catalysts for synergistic elimination of chloroaromatic organics and Nox." @default.
- W4309090180 created "2022-11-21" @default.
- W4309090180 creator A5020138151 @default.
- W4309090180 creator A5028214376 @default.
- W4309090180 creator A5032396875 @default.
- W4309090180 creator A5047974452 @default.
- W4309090180 creator A5058377867 @default.
- W4309090180 creator A5077314016 @default.
- W4309090180 date "2022-11-02" @default.
- W4309090180 modified "2023-09-26" @default.
- W4309090180 title "The Synergistic Catalysis of Chloroaromatic Organics and NOx over Monolithic Vanadium-Based Catalysts at Low Temperature" @default.
- W4309090180 cites W1963816342 @default.
- W4309090180 cites W1970789595 @default.
- W4309090180 cites W1972501641 @default.
- W4309090180 cites W1974187763 @default.
- W4309090180 cites W1979129921 @default.
- W4309090180 cites W1983061237 @default.
- W4309090180 cites W1986786491 @default.
- W4309090180 cites W1991311899 @default.
- W4309090180 cites W1996702839 @default.
- W4309090180 cites W2000601000 @default.
- W4309090180 cites W2004874036 @default.
- W4309090180 cites W2012871425 @default.
- W4309090180 cites W2026958518 @default.
- W4309090180 cites W2030813586 @default.
- W4309090180 cites W2035551885 @default.
- W4309090180 cites W2038610212 @default.
- W4309090180 cites W2040681670 @default.
- W4309090180 cites W2045411381 @default.
- W4309090180 cites W2049790452 @default.
- W4309090180 cites W2052465200 @default.
- W4309090180 cites W2053585628 @default.
- W4309090180 cites W2058659327 @default.
- W4309090180 cites W2062070604 @default.
- W4309090180 cites W2069776635 @default.
- W4309090180 cites W2070903087 @default.
- W4309090180 cites W2088840611 @default.
- W4309090180 cites W2135808028 @default.
- W4309090180 cites W2136868808 @default.
- W4309090180 cites W2155812595 @default.
- W4309090180 cites W2280838692 @default.
- W4309090180 cites W2281850587 @default.
- W4309090180 cites W2317264616 @default.
- W4309090180 cites W2509543230 @default.
- W4309090180 cites W2588485519 @default.
- W4309090180 cites W2725736143 @default.
- W4309090180 cites W2765604257 @default.
- W4309090180 cites W2770698596 @default.
- W4309090180 cites W2804999978 @default.
- W4309090180 cites W2877040459 @default.
- W4309090180 cites W2891546416 @default.
- W4309090180 cites W2918020190 @default.
- W4309090180 cites W2964751746 @default.
- W4309090180 cites W2967709337 @default.
- W4309090180 cites W2968917489 @default.
- W4309090180 cites W2976506752 @default.
- W4309090180 cites W3008118376 @default.
- W4309090180 cites W3092450354 @default.
- W4309090180 cites W3102272297 @default.
- W4309090180 cites W3165141238 @default.
- W4309090180 cites W3177163687 @default.
- W4309090180 cites W3198368038 @default.
- W4309090180 cites W3217168005 @default.
- W4309090180 cites W4200128949 @default.
- W4309090180 cites W4200339119 @default.
- W4309090180 cites W4235574122 @default.
- W4309090180 cites W4283066547 @default.
- W4309090180 cites W4283732947 @default.
- W4309090180 cites W4293201592 @default.
- W4309090180 doi "https://doi.org/10.3390/catal12111342" @default.
- W4309090180 hasPublicationYear "2022" @default.
- W4309090180 type Work @default.
- W4309090180 citedByCount "0" @default.
- W4309090180 crossrefType "journal-article" @default.
- W4309090180 hasAuthorship W4309090180A5020138151 @default.
- W4309090180 hasAuthorship W4309090180A5028214376 @default.
- W4309090180 hasAuthorship W4309090180A5032396875 @default.
- W4309090180 hasAuthorship W4309090180A5047974452 @default.
- W4309090180 hasAuthorship W4309090180A5058377867 @default.
- W4309090180 hasAuthorship W4309090180A5077314016 @default.
- W4309090180 hasBestOaLocation W43090901801 @default.
- W4309090180 hasConcept C105923489 @default.
- W4309090180 hasConcept C118792377 @default.
- W4309090180 hasConcept C127413603 @default.
- W4309090180 hasConcept C150394285 @default.
- W4309090180 hasConcept C150581940 @default.
- W4309090180 hasConcept C15752686 @default.
- W4309090180 hasConcept C161790260 @default.
- W4309090180 hasConcept C175708663 @default.
- W4309090180 hasConcept C178790620 @default.
- W4309090180 hasConcept C179104552 @default.
- W4309090180 hasConcept C185592680 @default.
- W4309090180 hasConcept C203032635 @default.
- W4309090180 hasConcept C27923307 @default.
- W4309090180 hasConcept C42360764 @default.
- W4309090180 hasConcept C504678139 @default.
- W4309090180 hasConcept C540031477 @default.
- W4309090180 hasConcept C55904794 @default.