Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309107142> ?p ?o ?g. }
- W4309107142 endingPage "108976" @default.
- W4309107142 startingPage "108976" @default.
- W4309107142 abstract "CHF 3 is considered as one kind of super greenhouse gases with extremely high global warming potential which is the byproduct during the manufacture of HCFC-22 (CHClF 2 ). Treatment CHF 3 via F/Cl exchange reaction with CHCl 3 forming CHCl 2 F and CHClF 2 is a potential resource utilization route rather than high energy-demanding incineration. The results confirmed that the crystal structures of Al-based fluorides were important to the catalytic activity due to it affects the availabilities of the Lewis acid sites. Through the DFT calculation, it found that AlClxFy species acted as the active sites for the CHF 3 conversion could decrease the energy barrier for the cleavage of C-F bonds. Furthermore, XPS analysis depicted that lower binding energy of Al-F was more likely to be partially chlorinated to formation AlClxFy species. Correspondingly, θ-AlF 3 showed the best catalytic performance for the CHF 3 conversion (30%) as well as less coke deposition contributed by the suitable Lewis acidic intensity. • θ-AlF 3 exhibits the highest CHF 3 F/Cl exchange reaction. • Phase structure of Al-based fluorides affects the availabilities of Lewis acid sites. • Lower Al-F binding energy is feasible to the chlorination of the catalysts. • AlClxFy is feasible to the cleavage of C-F bonds in CHF 3 ." @default.
- W4309107142 created "2022-11-22" @default.
- W4309107142 creator A5006850220 @default.
- W4309107142 creator A5009047806 @default.
- W4309107142 creator A5014528965 @default.
- W4309107142 creator A5017459794 @default.
- W4309107142 creator A5017474350 @default.
- W4309107142 creator A5025095617 @default.
- W4309107142 creator A5028867068 @default.
- W4309107142 creator A5032441946 @default.
- W4309107142 creator A5045486427 @default.
- W4309107142 creator A5071437727 @default.
- W4309107142 creator A5076960417 @default.
- W4309107142 creator A5079594267 @default.
- W4309107142 date "2022-12-01" @default.
- W4309107142 modified "2023-10-16" @default.
- W4309107142 title "Tame the super greenhouse gas-CHF3 via F/Cl exchange reaction over partially chlorinated Al-based fluoride catalysts" @default.
- W4309107142 cites W1969351094 @default.
- W4309107142 cites W1970127494 @default.
- W4309107142 cites W1979544533 @default.
- W4309107142 cites W1981368803 @default.
- W4309107142 cites W1982350596 @default.
- W4309107142 cites W1990256046 @default.
- W4309107142 cites W1994204043 @default.
- W4309107142 cites W1995368512 @default.
- W4309107142 cites W2006974102 @default.
- W4309107142 cites W2007395042 @default.
- W4309107142 cites W2009568094 @default.
- W4309107142 cites W2016253804 @default.
- W4309107142 cites W2021666014 @default.
- W4309107142 cites W2028919531 @default.
- W4309107142 cites W2033274629 @default.
- W4309107142 cites W2058292283 @default.
- W4309107142 cites W2061335046 @default.
- W4309107142 cites W2061507111 @default.
- W4309107142 cites W2063090574 @default.
- W4309107142 cites W2063167671 @default.
- W4309107142 cites W2064382286 @default.
- W4309107142 cites W2074588470 @default.
- W4309107142 cites W2078207667 @default.
- W4309107142 cites W2079493181 @default.
- W4309107142 cites W2081979752 @default.
- W4309107142 cites W2083267738 @default.
- W4309107142 cites W2085108613 @default.
- W4309107142 cites W2085264552 @default.
- W4309107142 cites W2103313166 @default.
- W4309107142 cites W2276707775 @default.
- W4309107142 cites W2290915816 @default.
- W4309107142 cites W2320043075 @default.
- W4309107142 cites W2475085295 @default.
- W4309107142 cites W251115972 @default.
- W4309107142 cites W2562629497 @default.
- W4309107142 cites W2615322403 @default.
- W4309107142 cites W2625838247 @default.
- W4309107142 cites W2763953464 @default.
- W4309107142 cites W2789897536 @default.
- W4309107142 cites W2888219264 @default.
- W4309107142 cites W2912344635 @default.
- W4309107142 cites W2952621519 @default.
- W4309107142 cites W3002235605 @default.
- W4309107142 cites W3090041485 @default.
- W4309107142 cites W3118360940 @default.
- W4309107142 cites W4200170448 @default.
- W4309107142 doi "https://doi.org/10.1016/j.jece.2022.108976" @default.
- W4309107142 hasPublicationYear "2022" @default.
- W4309107142 type Work @default.
- W4309107142 citedByCount "0" @default.
- W4309107142 crossrefType "journal-article" @default.
- W4309107142 hasAuthorship W4309107142A5006850220 @default.
- W4309107142 hasAuthorship W4309107142A5009047806 @default.
- W4309107142 hasAuthorship W4309107142A5014528965 @default.
- W4309107142 hasAuthorship W4309107142A5017459794 @default.
- W4309107142 hasAuthorship W4309107142A5017474350 @default.
- W4309107142 hasAuthorship W4309107142A5025095617 @default.
- W4309107142 hasAuthorship W4309107142A5028867068 @default.
- W4309107142 hasAuthorship W4309107142A5032441946 @default.
- W4309107142 hasAuthorship W4309107142A5045486427 @default.
- W4309107142 hasAuthorship W4309107142A5071437727 @default.
- W4309107142 hasAuthorship W4309107142A5076960417 @default.
- W4309107142 hasAuthorship W4309107142A5079594267 @default.
- W4309107142 hasConcept C161790260 @default.
- W4309107142 hasConcept C178790620 @default.
- W4309107142 hasConcept C179104552 @default.
- W4309107142 hasConcept C185592680 @default.
- W4309107142 hasConcept C18903297 @default.
- W4309107142 hasConcept C2780828025 @default.
- W4309107142 hasConcept C47737302 @default.
- W4309107142 hasConcept C86803240 @default.
- W4309107142 hasConceptScore W4309107142C161790260 @default.
- W4309107142 hasConceptScore W4309107142C178790620 @default.
- W4309107142 hasConceptScore W4309107142C179104552 @default.
- W4309107142 hasConceptScore W4309107142C185592680 @default.
- W4309107142 hasConceptScore W4309107142C18903297 @default.
- W4309107142 hasConceptScore W4309107142C2780828025 @default.
- W4309107142 hasConceptScore W4309107142C47737302 @default.
- W4309107142 hasConceptScore W4309107142C86803240 @default.
- W4309107142 hasIssue "6" @default.
- W4309107142 hasLocation W43091071421 @default.