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- W4309148077 endingPage "10575" @default.
- W4309148077 startingPage "10556" @default.
- W4309148077 abstract "Structural and transport properties of a newly designed high-transference number electrolyte (HTNE) system consisting of perfluoropolyether-block-poly(ethylene oxide) (PFPE-PEO; PFPEE10-Diol) as the solvent in a mixture with the lithium salt bis(trifluoromethanesulfonyl)imide (LiTFSI) for application in lithium-ion batteries (LIBs) are studied by molecular dynamics (MD) simulation. The obtained results indicate a correlation between the transference number (t+) and ionic conductivity (σ) of Li+. Therefore, an effective ionic conductivity parameter (σt+) is introduced to treat the transport properties of the electrolyte system. Analysis of the results leads to the conclusion that at a high temperature (423 K) and a salt (LiTFSI) concentration of 0.89 M, the studied HTNE system (PFPEE10) would show the highest performance, especially more efficient charge transfer, if employed as an electrolyte, in the LIB operation." @default.
- W4309148077 created "2022-11-23" @default.
- W4309148077 creator A5036285731 @default.
- W4309148077 creator A5040003176 @default.
- W4309148077 creator A5041947129 @default.
- W4309148077 creator A5051538383 @default.
- W4309148077 creator A5060502879 @default.
- W4309148077 date "2022-11-16" @default.
- W4309148077 modified "2023-10-13" @default.
- W4309148077 title "Structural and Transport Properties of Novel High-Transference Number Electrolytes Based on Perfluoropolyether-<i>block</i>-Poly(ethylene oxide) for Application in Lithium-Ion Batteries: A Molecular Dynamics Simulation Study" @default.
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