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- W4309148654 abstract "A ring distortion strategy was applied to the synthesis of a series of intramolecular cross-coupled analogues of forskolin 1. Treatment with palladium acetate, forskolin underwent an intramolecular cross-coupling reaction to generate a novel cycloalkene ether 2 in 85% yield. Under the same conditions, a series of forskolin ester analogues 4a-4d were prepared from 1-OH ester derivatives of forskolin 3a-3d in 85–93% yields. Treating cycloalkene ether 2 with aryl iodides in the presence of a palladium catalyst afforded Z-isomers arylation products 5a-5e in a stereoselective manner in 70–85% yields." @default.
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- W4309148654 date "2023-01-01" @default.
- W4309148654 modified "2023-10-16" @default.
- W4309148654 title "Synthesis of intramolecular cross-coupling analogues of forskolin" @default.
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- W4309148654 doi "https://doi.org/10.1016/j.fitote.2022.105353" @default.
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