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- W4309204219 endingPage "113034" @default.
- W4309204219 startingPage "113034" @default.
- W4309204219 abstract "Microemulsions (µEs), comprising water as polar component, pluronic (normal, L35 and reverse, 10R5) as surfactant and a hydrophobic ionic liquid (HIL) as non-polar component have been prepared and characterized. Owing to higher surface activity, pluronics have promoted the formation of µEs without the use of co-surfactant. Thus prepared µEs have been utilized as nano-reactors for the oxidation of guaiacol in the presence of Cytochrome-c (Cyt-c) at 15, 20, and 25 °C. A 3.2- and 1.3-fold increase in the rate of formation of product of enzymatic catalysis in direct µE (HIL-in-water) with reverse pluronic (10R5) is observed at 15 and 20 °C as compared to that in buffer. However, negligible enzymatic activity is observed in the direct µE formed by normal pluronic (L35). The catalytic activity of Cyt-c decreases in reverse µEs (water-in-HIL) as compared to direct µEs irrespective of the nature of pluronic used. The contrasting nature of nano-interfaces formed by pluronics in µEs and the extent of hydration of these nano-interfaces controlled by temperature exerts varying influence on the catalytic activity of Cyt-c. It is expected that the present work would result in providing a versatile platform for the creation of new IL and pluronic-based µEs for bio-catalytic applications, which have never been reported." @default.
- W4309204219 created "2022-11-24" @default.
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- W4309204219 date "2023-02-01" @default.
- W4309204219 modified "2023-09-24" @default.
- W4309204219 title "Water-pluronic-ionic liquid based microemulsions: Preparation, characterization and application as micro-reactor for enhanced catalytic activity of Cytochrome-c" @default.
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- W4309204219 doi "https://doi.org/10.1016/j.colsurfb.2022.113034" @default.
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