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- W4309279713 abstract "It was shown experimentally that interaction of polynuclear hexafluoroacetylacetonates [Cu4(hfac)4(MeO)4] and [Cu11(hfac)10(OH)8(O)2]·2C7H8 with nitronyl nitroxide radicals as well as their recrystallization in the presence of acetone led to complexes containing tetranuclear fragment {Cu4(hfac)2(LHF)x(LF)2-x} (x = 0–2), where LHF and LF are triply charged anions of 2-methyl-4,6-bis(trifluoromethyl)tetrahydropyran-2,4,6-triol and 2,4,6-tris(trifluoromethyl)tetrahydropyran-2,4,6-triol, respectively. The main factors contributing to the formation of the 4-nuclear fragment and trioxanes LHF and LF were identified. It is established that self-assembly of {Cu4(hfac)2(LHF)x(LF)2-x} is observed only in the case of mono- and polynuclear CuII hexafluoroacetylacetonates. For CoII and NiII compounds the formation of such a fragment is not registered." @default.
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- W4309279713 date "2023-01-01" @default.
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- W4309279713 title "Self-assembly of the 4-nuclear fragment {Cu4(hfac)2(LHF) (LF)2-} with deprotonated trihydroxyoxanes and heterospin complexes with nitroxides" @default.
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- W4309279713 doi "https://doi.org/10.1016/j.poly.2022.116209" @default.
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