FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309331044> ?p ?o ?g. }

• W4309331044 endingPage "8794" @default.
• W4309331044 startingPage "8786" @default.
• W4309331044 abstract "The polyaddition between dicyclic carbonates and diamines leading to poly(hydroxy urethane)s (PHUs) has emerged as the preferred method for the synthesis of green, non-isocyanate polyurethanes. However, when proposed for use as structural adhesives, the long times for completion of aminolysis of the 5-membered cyclic carbonates under ambient conditions force the use of complementary chemistries to accelerate the curing process. In this work, a system that combines an amino-terminated PHU (NH2–PHU–NH2), an epoxy resin, and a thiol compound was employed to develop high-shear strength PHU-epoxy hybrid adhesives able to cure at room temperature in short times. A NH2–PHU–NH2 prepolymer synthesized by using a sub-stoichiometric quantity of dicyclic carbonates was mixed with a bisphenol A-based epoxy resin for the preparation of the structural adhesive. While this adhesive showed good lap-shear strength and shear resistance under static load and temperature, the curing process was slow. In order to speed up the curing process, a thiol (trimethylolpropane tris(3-mercapto propionate)) was added and its impact on the curing process as well as on the adhesive properties was evaluated. The trifunctional thiol additive allowed for faster curing in the presence of the 1,1,3,3-tetramethylguanidine basic catalyst. Moreover, a combination of NH2–PHU–NH2 and the thiol as curing agents for the epoxy resin resulted in adhesives with superior toughness, without any deterioration of the ultimate lap-shear strength or shear resistance under load and temperature, making these adhesives suitable for high-demand applications in the automotive industry." @default.
• W4309331044 created "2022-11-26" @default.
• W4309331044 creator A5009936560 @default.
• W4309331044 creator A5012810514 @default.
• W4309331044 creator A5038712399 @default.
• W4309331044 creator A5050721307 @default.
• W4309331044 creator A5055169937 @default.
• W4309331044 date "2022-11-16" @default.
• W4309331044 modified "2023-09-30" @default.
• W4309331044 title "Accelerating the Curing of Hybrid Poly(Hydroxy Urethane)-Epoxy Adhesives by the Thiol-Epoxy Chemistry" @default.
• W4309331044 cites W1207884610 @default.
• W4309331044 cites W189270114 @default.
• W4309331044 cites W1965833152 @default.
• W4309331044 cites W1979413815 @default.
• W4309331044 cites W1989149290 @default.
• W4309331044 cites W1994565690 @default.
• W4309331044 cites W2018277210 @default.
• W4309331044 cites W2038297325 @default.
• W4309331044 cites W2047903920 @default.
• W4309331044 cites W2052954191 @default.
• W4309331044 cites W2063144771 @default.
• W4309331044 cites W2067558555 @default.
• W4309331044 cites W2087430147 @default.
• W4309331044 cites W2100848905 @default.
• W4309331044 cites W2122635045 @default.
• W4309331044 cites W2132341534 @default.
• W4309331044 cites W2153788147 @default.
• W4309331044 cites W2269030652 @default.
• W4309331044 cites W2330924637 @default.
• W4309331044 cites W2468317771 @default.
• W4309331044 cites W2609333415 @default.
• W4309331044 cites W2753454474 @default.
• W4309331044 cites W2766140685 @default.
• W4309331044 cites W2767358772 @default.
• W4309331044 cites W2898837112 @default.
• W4309331044 cites W2911499577 @default.
• W4309331044 cites W2980280110 @default.
• W4309331044 cites W3012959278 @default.
• W4309331044 cites W3040973148 @default.
• W4309331044 cites W3048114322 @default.
• W4309331044 cites W3109596824 @default.
• W4309331044 cites W3111946337 @default.
• W4309331044 cites W3122040105 @default.
• W4309331044 cites W3180084182 @default.
• W4309331044 cites W4206166453 @default.
• W4309331044 cites W4206243172 @default.
• W4309331044 cites W4254171932 @default.
• W4309331044 doi "https://doi.org/10.1021/acsapm.2c01195" @default.
• W4309331044 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36532887" @default.
• W4309331044 hasPublicationYear "2022" @default.
• W4309331044 type Work @default.
• W4309331044 citedByCount "3" @default.
• W4309331044 countsByYear W43093310442023 @default.
• W4309331044 crossrefType "journal-article" @default.
• W4309331044 hasAuthorship W4309331044A5009936560 @default.
• W4309331044 hasAuthorship W4309331044A5012810514 @default.
• W4309331044 hasAuthorship W4309331044A5038712399 @default.
• W4309331044 hasAuthorship W4309331044A5050721307 @default.
• W4309331044 hasAuthorship W4309331044A5055169937 @default.
• W4309331044 hasBestOaLocation W43093310441 @default.
• W4309331044 hasConcept C132976073 @default.
• W4309331044 hasConcept C159985019 @default.
• W4309331044 hasConcept C166595027 @default.
• W4309331044 hasConcept C185592680 @default.
• W4309331044 hasConcept C188027245 @default.
• W4309331044 hasConcept C192562407 @default.
• W4309331044 hasConcept C2776949262 @default.
• W4309331044 hasConcept C2779227376 @default.
• W4309331044 hasConcept C2779578285 @default.
• W4309331044 hasConcept C68928338 @default.
• W4309331044 hasConceptScore W4309331044C132976073 @default.
• W4309331044 hasConceptScore W4309331044C159985019 @default.
• W4309331044 hasConceptScore W4309331044C166595027 @default.
• W4309331044 hasConceptScore W4309331044C185592680 @default.
• W4309331044 hasConceptScore W4309331044C188027245 @default.
• W4309331044 hasConceptScore W4309331044C192562407 @default.
• W4309331044 hasConceptScore W4309331044C2776949262 @default.
• W4309331044 hasConceptScore W4309331044C2779227376 @default.
• W4309331044 hasConceptScore W4309331044C2779578285 @default.
• W4309331044 hasConceptScore W4309331044C68928338 @default.
• W4309331044 hasFunder F4320321390 @default.
• W4309331044 hasFunder F4320321705 @default.
• W4309331044 hasFunder F4320321919 @default.
• W4309331044 hasFunder F4320335322 @default.
• W4309331044 hasFunder F4320338337 @default.
• W4309331044 hasIssue "12" @default.
• W4309331044 hasLocation W43093310441 @default.
• W4309331044 hasLocation W43093310442 @default.
• W4309331044 hasLocation W43093310443 @default.
• W4309331044 hasLocation W43093310444 @default.
• W4309331044 hasOpenAccess W4309331044 @default.
• W4309331044 hasPrimaryLocation W43093310441 @default.
• W4309331044 hasRelatedWork W1995958177 @default.
• W4309331044 hasRelatedWork W2019117994 @default.
• W4309331044 hasRelatedWork W2026477024 @default.
• W4309331044 hasRelatedWork W2092814777 @default.
• W4309331044 hasRelatedWork W2356846522 @default.
• W4309331044 hasRelatedWork W2366864285 @default.

• next