Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309357476> ?p ?o ?g. }
- W4309357476 abstract "Abstract Cooperativity among spin centres has long been the royal road to impose magnetic bistability in terms of thermal hysteresis. In this work we access magnetic multi-metastability of the iron(III) complex [Fe(L) 2 ][BPh 4 ] ( 1 ) at low temperature, in addition to thermal bistability. The packing of the low-spin and high-spin forms of crystalline 1 differs only marginally what ultimately leads to very minor thermal variation in the lattice constants. This indicates that the SCO-immanent breathing of the complex cation is almost fully compensated by the anion matrix. We believe that this structural conservatism is the origin of the unique cooling-rate dependence of the residual low-temperature magnetisation in 1 . The system state of 1 can be continuously tuned between the trapped high-spin (ON) and the relaxed low-spin state (OFF), as a simple function of the cooling rate. That is, cooperative spin crossover can be the source of bistable and multi-metastable system states in the very same material." @default.
- W4309357476 created "2022-11-26" @default.
- W4309357476 creator A5011319767 @default.
- W4309357476 creator A5013755835 @default.
- W4309357476 creator A5032109714 @default.
- W4309357476 creator A5040948012 @default.
- W4309357476 creator A5051317911 @default.
- W4309357476 creator A5075677720 @default.
- W4309357476 date "2022-11-18" @default.
- W4309357476 modified "2023-10-17" @default.
- W4309357476 title "Cooperative spin crossover: analog to digital – and back" @default.
- W4309357476 cites W1783921891 @default.
- W4309357476 cites W1906121697 @default.
- W4309357476 cites W1968352183 @default.
- W4309357476 cites W1978495639 @default.
- W4309357476 cites W1995187922 @default.
- W4309357476 cites W1997884116 @default.
- W4309357476 cites W2004362095 @default.
- W4309357476 cites W2005642160 @default.
- W4309357476 cites W2014916013 @default.
- W4309357476 cites W2017499093 @default.
- W4309357476 cites W2033738538 @default.
- W4309357476 cites W2035627959 @default.
- W4309357476 cites W2041655565 @default.
- W4309357476 cites W2045894490 @default.
- W4309357476 cites W2050867536 @default.
- W4309357476 cites W2058157731 @default.
- W4309357476 cites W2064311755 @default.
- W4309357476 cites W2072834473 @default.
- W4309357476 cites W2091992259 @default.
- W4309357476 cites W2095393968 @default.
- W4309357476 cites W2096031132 @default.
- W4309357476 cites W2113955540 @default.
- W4309357476 cites W2123194805 @default.
- W4309357476 cites W2134561959 @default.
- W4309357476 cites W2138930032 @default.
- W4309357476 cites W2139668109 @default.
- W4309357476 cites W2147743015 @default.
- W4309357476 cites W2163185964 @default.
- W4309357476 cites W2172030852 @default.
- W4309357476 cites W2298805510 @default.
- W4309357476 cites W2299447723 @default.
- W4309357476 cites W2312589207 @default.
- W4309357476 cites W2338340524 @default.
- W4309357476 cites W2516617512 @default.
- W4309357476 cites W2792030391 @default.
- W4309357476 cites W2892252556 @default.
- W4309357476 cites W2909302712 @default.
- W4309357476 cites W2936659100 @default.
- W4309357476 cites W2950737075 @default.
- W4309357476 cites W2966625239 @default.
- W4309357476 cites W2980653700 @default.
- W4309357476 cites W2982222559 @default.
- W4309357476 cites W2989907928 @default.
- W4309357476 cites W3007991680 @default.
- W4309357476 cites W3034422183 @default.
- W4309357476 cites W3083279643 @default.
- W4309357476 cites W3178160438 @default.
- W4309357476 cites W3198190758 @default.
- W4309357476 cites W4211172937 @default.
- W4309357476 cites W4214941314 @default.
- W4309357476 cites W4231960227 @default.
- W4309357476 cites W4242981715 @default.
- W4309357476 cites W4246233064 @default.
- W4309357476 doi "https://doi.org/10.21203/rs.3.rs-2145792/v1" @default.
- W4309357476 hasPublicationYear "2022" @default.
- W4309357476 type Work @default.
- W4309357476 citedByCount "1" @default.
- W4309357476 countsByYear W43093574762023 @default.
- W4309357476 crossrefType "posted-content" @default.
- W4309357476 hasAuthorship W4309357476A5011319767 @default.
- W4309357476 hasAuthorship W4309357476A5013755835 @default.
- W4309357476 hasAuthorship W4309357476A5032109714 @default.
- W4309357476 hasAuthorship W4309357476A5040948012 @default.
- W4309357476 hasAuthorship W4309357476A5051317911 @default.
- W4309357476 hasAuthorship W4309357476A5075677720 @default.
- W4309357476 hasBestOaLocation W43093574761 @default.
- W4309357476 hasConcept C115260700 @default.
- W4309357476 hasConcept C121332964 @default.
- W4309357476 hasConcept C166014724 @default.
- W4309357476 hasConcept C185592680 @default.
- W4309357476 hasConcept C192562407 @default.
- W4309357476 hasConcept C204530211 @default.
- W4309357476 hasConcept C26873012 @default.
- W4309357476 hasConcept C2777222292 @default.
- W4309357476 hasConcept C32546565 @default.
- W4309357476 hasConcept C35325081 @default.
- W4309357476 hasConcept C55493867 @default.
- W4309357476 hasConcept C62520636 @default.
- W4309357476 hasConcept C89464430 @default.
- W4309357476 hasConcept C97292510 @default.
- W4309357476 hasConcept C97355855 @default.
- W4309357476 hasConceptScore W4309357476C115260700 @default.
- W4309357476 hasConceptScore W4309357476C121332964 @default.
- W4309357476 hasConceptScore W4309357476C166014724 @default.
- W4309357476 hasConceptScore W4309357476C185592680 @default.
- W4309357476 hasConceptScore W4309357476C192562407 @default.
- W4309357476 hasConceptScore W4309357476C204530211 @default.
- W4309357476 hasConceptScore W4309357476C26873012 @default.
- W4309357476 hasConceptScore W4309357476C2777222292 @default.