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• W4309410720 abstract "Abstract A non‐aromatic expanded carbaporphyrinoid, incorporating two built‐in 2,7‐pyrenylene moieties was synthesized. The intrinsically labile structure was demonstrated by proton‐triggered conformational changes between the figure‐of‐eight and quasi‐Möbius conformers. Upon treatment with Pd(OAc) 2 , the reaction produces two bis‐Pd II complexes with distinct coordination modes. Metal coordination serves to fix the macrocyclic frameworks with the net result that both bis‐Pd II complexes could be resolved by high performance liquid chromatography (HPLC) on a chiral stationary phase. The isolated enantiomers showed persistent chiroptical properties as evidenced by the intense response in the circular dichroism (CD) spectra and the record high absorption dissymmetry factors ( g abs of up to 0.038) seen in the near‐infrared spectral region. Moreover, the mutual interconversion of these two Pd II complexes was found to be stereospecific and to favor the more stable isomers under weakly acidic conditions." @default.
• W4309410720 created "2022-11-27" @default.
• W4309410720 creator A5000215293 @default.
• W4309410720 creator A5022499603 @default.
• W4309410720 creator A5025184521 @default.
• W4309410720 creator A5039955869 @default.
• W4309410720 creator A5061592533 @default.
• W4309410720 creator A5065172118 @default.
• W4309410720 creator A5084593909 @default.
• W4309410720 date "2022-12-12" @default.
• W4309410720 modified "2023-10-17" @default.
• W4309410720 title "Di‐2,7‐pyrenidecaphyrin(1.1.0.0.0.1.1.0.0.0) and Its Bis‐Organopalladium Complexes: Synthesis and Chiroptical Properties" @default.
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• W4309410720 doi "https://doi.org/10.1002/anie.202212770" @default.
• W4309410720 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36401592" @default.
• W4309410720 hasPublicationYear "2022" @default.

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