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• W4309457211 abstract "2-deoxythiosugars are more stable than 2-deoxysugars occurring broadly in bioactive natural products and pharmaceutical agents. An effective and direct methodology to stereoselectively synthesize α-2-deoxythioglycosides catalyzed by AgOTf has been developed. Various alkyl thiols and thiophenols were explored and the desired products were formed in good yields with excellent α-selectivity. This method was further applied to the syntheses of S-linked disaccharides and late-stage 2-deoxyglycosylation of estrogen, L-menthol, and zingerone thiols successfully." @default.
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• W4309457211 date "2022-11-17" @default.
• W4309457211 modified "2023-10-16" @default.
• W4309457211 title "Stereoselective Synthesis of 2-Deoxythiosugars from Glycals" @default.
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• W4309457211 doi "https://doi.org/10.3390/molecules27227979" @default.
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