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- W4309485400 abstract "This study aims to conduct statistical optimization of nZVI synthesis parameters towards the removal efficiency of phosphorus (P) and nitrate (NO3-), considering for the first time the cost-effectiveness index. The detailed statistical analysis was implemented to evaluate the main effects and interactions of eight synthesis parameters, including reductant concentration (RC), reductant delivery rate (RDR), reductant liquid volume (RLV), pH, aging time (AGT), mixing speed (MS), temperature (T), and precursor concentration (PC). Results revealed that the experimental optimization of the synthesis factors improved the removal efficiency of NO3- and P by 27 and 9%, respectively, with respect to that before the optimization. ANOVA statistical results indicated the significance of RP (%) and [Formula: see text] (%) models with F-values of 4.480 × 108 and 23,755.08, respectively. Moreover, the p-values of all the eight main linear effects were less than 0.05 in both two models of RP (%) and [Formula: see text] (%). However, most of the interaction parameters were not statistically significant (higher than 0.05) in the case of [Formula: see text] (%), which is unlike RP (%) where all interaction parameters were statistically significant (less than 0.05). The normal probability plots of factors effects provided significant evidence of the significance of the investigated parameters RC had the highest positive statistically significant effect on RP (%) followed by RLV, RDR, MS and T. In case of [Formula: see text] (%), RLV had the highest positive significant effect, followed by AGT > RDR > pH > T > MS. The cost-effective optimal constraints in this study resulted in the best economically optimized values of the nZVI synthesis parameters in terms of higher reactivity and reduced synthesis cost." @default.
- W4309485400 created "2022-11-28" @default.
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- W4309485400 date "2023-01-01" @default.
- W4309485400 modified "2023-09-30" @default.
- W4309485400 title "Statistical optimization of nZVI chemical synthesis approach towards P and NO3− removal from aqueous solutions: Cost-effectiveness & parametric effects" @default.
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- W4309485400 doi "https://doi.org/10.1016/j.chemosphere.2022.137176" @default.
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