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- W4309575770 abstract "Herein, gold-nanoclusters Au6(SR)6 are synthesized in the argon atmosphere, using 2-phenylethanethiol and tetraoctylammonium bromide, as ligands and surfactants, respectively. Au6(SR)6 possesses ca. 1.95 eV HOMO-LUMO gap, which is comparatively high and is also a dominant factor for quantum confinement effect. Moreover, the X-ray Photoelectron Spectroscopy (XPS) study shows the peak of Au 4f7/2 appears at 86.89 eV, which describes the consistency regarding the size of clusters with XPS peak shift for Au 4f7/2 value. In addition, the full width half maximum (FWHM) increases accordingly by decreasing the size of clusters." @default.
- W4309575770 created "2022-11-28" @default.
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- W4309575770 date "2023-01-01" @default.
- W4309575770 modified "2023-10-14" @default.
- W4309575770 title "Synthesis and study of the quantum-confinement effect of gold-nanoclusters via optical properties protected by 2-phenylethanethiol ligand" @default.
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- W4309575770 doi "https://doi.org/10.1016/j.cplett.2022.140206" @default.
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