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- W4309592389 abstract "2,2[Formula: see text]-Biphenyl-fused Ni(II) porphyrins were synthesized by two methods. One was oxidative fusion reaction of meso-(biphen-2-yl)-substituted Ni(II) porphyrin with the combination of 2,3-dichloro-5,6-dicyano-[Formula: see text]-benzoquinone (DDQ) and Sc(OTf) 3 and the other was Pd-catalyzed intramolecular cyclization of meso-(2[Formula: see text]-chlorobiphen-2-yl)-substituted Ni(II) porphyrin. These fused products showed contorted structures owing to the installed seven-membered carbocycle(s) that were revealed by X-ray crystallographic analysis and exhibited moderately red-shifted absorption bands." @default.
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- W4309592389 date "2022-11-19" @default.
- W4309592389 modified "2023-10-16" @default.
- W4309592389 title "Synthesis of 2,2′-biphenyl-fused porphyrins: Installation of directly fused seven-membered ring" @default.
- W4309592389 doi "https://doi.org/10.1142/s1088424622500663" @default.
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