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- W4309626791 abstract "An efficient and stereospecific azidation of a cis -disubstituted azepane is described as the first example of hypervalent silicate-assisted nucleophilic azidation on a substituted seven-membered azepane ring. DFT calculations suggest an S N 2-like mechanism whereby the azido nucleophile coordinated to the hypervalent silicate presents flexible geometries for the nucleophilic approach. The method provides a viable alternative to the classical Mitsunobu-based approaches in substituted seven-membered N -heterocycles with complex conformational properties." @default.
- W4309626791 created "2022-11-28" @default.
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- W4309626791 date "2022-12-01" @default.
- W4309626791 modified "2023-09-29" @default.
- W4309626791 title "Hypervalent silicate-assisted azidation approach for the substituted azepane motif" @default.
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- W4309626791 doi "https://doi.org/10.1016/j.tetlet.2022.154245" @default.
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