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- W4309643721 abstract "Abstract V 2 CT x shows a low ion diffusion barrier, while the multiple oxidation states of vanadium allow V 2 CT x to participate in multi-electron redox reactions, which demonstrates a greater potential for electrochemical energy storage applications. However, the lateral arrangement of V 2 CT x lamellae tends to cause the accumulation and collapse of the structure. Herein, the two-dimensional layered V 2 CT x is modified with Ag + and Cu 2+ , the V 2 CT x /Ag/Cu composite is successfully prepared. The Ag nanoparticles (NPs) and Cu NPs grown between the layers of V 2 CT x can effectively suppress the accumulation of the lamellae and ensure the smooth transfer of electrolyte ions and electrons between the layers. Meanwhile, the doping of Ag NPs and Cu NPs can enlarge the interlayer spacing of V 2 CT x , which can expose more active contact sites for electrolyte ions, shorten the diffusion path of electrolyte ions, and effectively improve the electrochemical performance of V 2 CT x . The Ag NPs and Cu NPs agglomerate in the delamination of V 2 CT x to form a conductive channel covering multiple layers, which facilitates cross-layer electron transfer and reduces the internal resistance of the V 2 CT x /Ag/Cu composite. Basis on the above reasonable structural designs, the internal resistance of the V 2 CT x /Ag/Cu composite is only 0.72 Ω, showing excellent diffusion ability of K + . The result represents a new step forward in exploring the electrochemical properties of two dimensional materials of V 2 CT x ." @default.
- W4309643721 created "2022-11-28" @default.
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- W4309643721 date "2022-12-05" @default.
- W4309643721 modified "2023-10-18" @default.
- W4309643721 title "Facile self-assembly of sandwich-like MXene layered multiscale structure nanocomposite" @default.
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- W4309643721 doi "https://doi.org/10.1088/2053-1583/aca4e1" @default.
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