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• W4309708487 abstract "This investigation reports on the thermomechanical properties of Poly-tripropyleneglycoldiacrylate (Poly-TPGDA)/liquid crystal (LC) blends, developed via free radical polymerization processes, which are induced by Electron Beam (EB) and Ultraviolet (UV) radiation. The EB-cured Poly-TPGDA network exhibits a higher glass transition temperature (Tg), a higher tensile storage, and Young moduli than the corresponding UV-cured sample, indicating a lower elasticity and a shorter distance between the two adjacent crosslinking points. Above Tg of Poly-TPGDA/LC blends, the LC behaves as a plasticizing agent, whereas, for EB-cured networks, at temperatures below Tg, the LC shows a strong temperature dependence on the storage tensile modulus: the LC reinforces the polymer due to the presence of nano-sized phase separated glassy LC domains, confirmed by electron microscopy observations. In the case of the UV-cured TPGDA/LC system, the plasticizing effect of the LC remains dominant in both the whole composition and the temperature ranges explored. The rubber elasticity and Tg of Poly-TPGDA/LC films were investigated using mechanical measurements." @default.
• W4309708487 created "2022-11-29" @default.
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• W4309708487 date "2022-11-19" @default.
• W4309708487 modified "2023-10-13" @default.
• W4309708487 title "Temperature Controlled Mechanical Reinforcement of Polyacrylate Films Containing Nematic Liquid Crystals" @default.
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• W4309708487 doi "https://doi.org/10.3390/polym14225024" @default.
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