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- W4309770851 abstract "An enantioselective reaction of cyclic C-alkynyl imine precursor with thiols catalyzed by (R)-H8-TRIP has been described. A broad range of alkynyl isoindolinones possessing a single chiral quaternary center and an N,S-ketal framework were synthesized in high yields (up to 99%) and excellent enantioselectivity (up to 99% ee). The practicality of the methodology was depicted by a gram scale synthesis and interesting synthetic transformation of products." @default.
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- W4309770851 date "2022-12-01" @default.
- W4309770851 modified "2023-10-04" @default.
- W4309770851 title "Chiral phosphoric acid-catalyzed reaction between C-alkynyl imine precursor and thiol: Access to highly enantioenriched alkynyl isoindolinones with N,S-ketal framework" @default.
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- W4309770851 doi "https://doi.org/10.1016/j.tetlet.2022.154230" @default.
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