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• W4309773113 abstract "This work is focused on the synthesis and evaluation of cobalt oxides grown onto zirconia fibers by the Atomic Layer Deposition (ALD) technique. CO oxidation is a wide studied reaction so that it was used as a model for testing the synthesized catalysts. Morphological and physicochemical properties were investigated through various characterization techniques. The deposited loading of the active phase was low (<1.2 at.% in all samples), and it was dispersed homogeneously along the zirconium oxide with fiber morphology with an length/diameter aspect ratio of about 50. Bulk and surface analysis showed the presence of different cobalt species (Co2+ and Co3+) that allow obtaining active catalysts for the reaction under study. Both the total amount of cobalt and the proportion of Co3+ species were higher as the number of ALD cycles increased. Through stability experiments, a change in the active species was detected after various cycles of reaction. This modification led to an increase in the surface Co3+ amount with changes in the coordination state." @default.
• W4309773113 created "2022-11-29" @default.
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• W4309773113 date "2023-01-01" @default.
• W4309773113 modified "2023-10-10" @default.
• W4309773113 title "Cobalt oxide-based catalysts supported on zirconia fibers synthesized by atomic layer deposition" @default.
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• W4309773113 doi "https://doi.org/10.1016/j.matchemphys.2022.127043" @default.
• W4309773113 hasPublicationYear "2023" @default.
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