Matches in SemOpenAlex for { <https://semopenalex.org/work/W4309810323> ?p ?o ?g. }
- W4309810323 endingPage "20436" @default.
- W4309810323 startingPage "20423" @default.
- W4309810323 abstract "When linearly heating trehalose dihydrate (TH-DH) at a relatively high heating rate (β ≥ 1.5 K min–1), the thermal dehydration begins in the solid state and transitions to the liquid state at the melting point of TH-DH (∼370 K). The complex mass loss and phase change characteristics observed during the thermal dehydration is due to the contributory effects of various physical phenomena, including melting of TH-DH and anhydride products. The reactions entirely occurred in the solid state under isothermal and nonisothermal conditions at a low heating rate (β ≤ 1.0 K min–1), and its kinetics were described by the physico-geometrical consecutive process comprising the surface reaction and subsequent phase boundary-controlled reaction. The reactions initiated at approximately the melting point of TH-DH under a significantly high atmospheric water vapor pressure and proceeded mostly in the liquid state exhibiting a single-step mass loss behavior. The thermal dehydration accompanied by liquefaction demonstrated an autocatalytic kinetic behavior, which was regulated by the evaporation of the water vapor from the surface of viscous liquid particles. The kinetic findings for the reactions in the solid and liquid states allow the physico-geometrical interpretation for the complex mass loss and phase change behaviors during heating TH-DH at relatively high β values." @default.
- W4309810323 created "2022-11-29" @default.
- W4309810323 creator A5048876059 @default.
- W4309810323 creator A5051584281 @default.
- W4309810323 creator A5063758922 @default.
- W4309810323 creator A5080918594 @default.
- W4309810323 date "2022-11-23" @default.
- W4309810323 modified "2023-10-16" @default.
- W4309810323 title "Physico-geometrical Kinetic Aspects of the Thermal Dehydration of Trehalose Dihydrate" @default.
- W4309810323 cites W1965813194 @default.
- W4309810323 cites W1969408672 @default.
- W4309810323 cites W1972376417 @default.
- W4309810323 cites W1972693473 @default.
- W4309810323 cites W1973887862 @default.
- W4309810323 cites W1976747601 @default.
- W4309810323 cites W1976814956 @default.
- W4309810323 cites W1977146448 @default.
- W4309810323 cites W1981443157 @default.
- W4309810323 cites W1981554141 @default.
- W4309810323 cites W1988238765 @default.
- W4309810323 cites W1991974901 @default.
- W4309810323 cites W1999190098 @default.
- W4309810323 cites W2001554282 @default.
- W4309810323 cites W2003164425 @default.
- W4309810323 cites W2006614225 @default.
- W4309810323 cites W2008854263 @default.
- W4309810323 cites W2012257367 @default.
- W4309810323 cites W2012794851 @default.
- W4309810323 cites W2015875492 @default.
- W4309810323 cites W2018407867 @default.
- W4309810323 cites W2022660588 @default.
- W4309810323 cites W2024118271 @default.
- W4309810323 cites W2025103808 @default.
- W4309810323 cites W2032315291 @default.
- W4309810323 cites W2034002625 @default.
- W4309810323 cites W2037048726 @default.
- W4309810323 cites W2037572807 @default.
- W4309810323 cites W2038008598 @default.
- W4309810323 cites W2041443899 @default.
- W4309810323 cites W2042448543 @default.
- W4309810323 cites W2045224434 @default.
- W4309810323 cites W2048688220 @default.
- W4309810323 cites W2048979364 @default.
- W4309810323 cites W2051696465 @default.
- W4309810323 cites W2055108385 @default.
- W4309810323 cites W2056313043 @default.
- W4309810323 cites W2057490033 @default.
- W4309810323 cites W2061156599 @default.
- W4309810323 cites W2063532700 @default.
- W4309810323 cites W2075460550 @default.
- W4309810323 cites W2078452660 @default.
- W4309810323 cites W2079790580 @default.
- W4309810323 cites W2084777440 @default.
- W4309810323 cites W2085871110 @default.
- W4309810323 cites W2086270520 @default.
- W4309810323 cites W2088169918 @default.
- W4309810323 cites W2088389432 @default.
- W4309810323 cites W2088606248 @default.
- W4309810323 cites W2105345975 @default.
- W4309810323 cites W2121969139 @default.
- W4309810323 cites W2155439800 @default.
- W4309810323 cites W2160721112 @default.
- W4309810323 cites W2163439943 @default.
- W4309810323 cites W2313426671 @default.
- W4309810323 cites W2315477216 @default.
- W4309810323 cites W2321320069 @default.
- W4309810323 cites W2329561401 @default.
- W4309810323 cites W2330592286 @default.
- W4309810323 cites W2567855322 @default.
- W4309810323 cites W2613404063 @default.
- W4309810323 cites W2735302875 @default.
- W4309810323 cites W2792119482 @default.
- W4309810323 cites W2795851629 @default.
- W4309810323 cites W2805247170 @default.
- W4309810323 cites W2894706299 @default.
- W4309810323 cites W3025544282 @default.
- W4309810323 cites W3089296005 @default.
- W4309810323 cites W3159274658 @default.
- W4309810323 cites W3204866494 @default.
- W4309810323 cites W3209139331 @default.
- W4309810323 cites W4200559198 @default.
- W4309810323 cites W4235564499 @default.
- W4309810323 cites W4283644505 @default.
- W4309810323 doi "https://doi.org/10.1021/acs.jpcc.2c07104" @default.
- W4309810323 hasPublicationYear "2022" @default.
- W4309810323 type Work @default.
- W4309810323 citedByCount "2" @default.
- W4309810323 countsByYear W43098103232023 @default.
- W4309810323 crossrefType "journal-article" @default.
- W4309810323 hasAuthorship W4309810323A5048876059 @default.
- W4309810323 hasAuthorship W4309810323A5051584281 @default.
- W4309810323 hasAuthorship W4309810323A5063758922 @default.
- W4309810323 hasAuthorship W4309810323A5080918594 @default.
- W4309810323 hasConcept C121332964 @default.
- W4309810323 hasConcept C133347239 @default.
- W4309810323 hasConcept C13530604 @default.
- W4309810323 hasConcept C135889238 @default.
- W4309810323 hasConcept C148898269 @default.