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- W4309825536 abstract "In this study, we afford explicit characterizations of the electronic and geometrical structures of recently reported hypervalent penta-coordinate carbon compounds by using gas-phase characterization techniques: photodissociation spectroscopy (PDS) and ion mobility-mass spectrometry (IM-MS). In particular for a compound with moderately electron-donating ligands, bearing p-methylthiophenyl substituents, the coexistence of tetra- and penta-coordinate isomers is confirmed, consistent with solution characterizations. It is in sharp contrast to the exclusive tetra-coordinate form (with normal valence of the central carbon atom) in the single crystal. This suggests that a non-polar environment makes the penta-coordinate structure thermodynamically most stable. This delicate difference between the tetra- and penta-coordinate structures, which depends on the environment, is a close reflection of the lower activation barrier of the SN 2 reaction found in neutral solvent or gas-phase reactions." @default.
- W4309825536 created "2022-11-29" @default.
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- W4309825536 date "2023-01-19" @default.
- W4309825536 modified "2023-10-16" @default.
- W4309825536 title "Gas‐Phase Characterization of Hypervalent Carbon Compounds Bearing 7‐6‐7‐Ring Skeleton: Penta‐ <i>versus</i> Tetra‐Coordinate Isomers" @default.
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- W4309825536 doi "https://doi.org/10.1002/chem.202203163" @default.
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- W4309825536 hasPublicationYear "2023" @default.
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