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- W4309899493 abstract "Prior to being utilized in the body, dietary vitamin K homologues are converted to menaquinone-4 (MK-4) by cleavage of the side chain part followed by prenylation. We predicted that the prenylation would occur due to the electron deficiency at the C-1′ position of the allyl moiety. Therefore, as an alternative method to make the C-1′ position electron-deficient, a new vitamin K derivative was synthesized by introducing a ketone group, and its conversion to MK-4 was investigated. Introduction of a ketone group at the C-1′ position of the side chain of 2′,3′-dihydrophylloquinone, which is known to resist conversion to MK-4, induced conversion to the MK-4 analog to a degree similar to that of natural phylloquinone. Thus, the electron deficiency at the C-1′ position is important for the conversion to MK-4." @default.
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- W4309899493 date "2023-03-01" @default.
- W4309899493 modified "2023-09-30" @default.
- W4309899493 title "Synthesis of new vitamin K derivatives with a ketone group at the C-1′ position of the side chain and their conversion to menaquinone-4" @default.
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- W4309899493 doi "https://doi.org/10.1016/j.molstruc.2022.134614" @default.
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