Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310033003> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W4310033003 abstract "pH-responsive systems have gained importance for the development of smart materials and for biomedical applications because they can switch between different states by simple acid/base triggers. However, such equilibrium systems lack the autonomous behavior that is so ubiquitous in living systems that self-regulate out of equilibrium. As a contribution to the emerging field of autonomous chemical systems, we have developed pH feedback systems (pH-FS) based on the coupling of acid- and base-producing steps in chemical reaction networks. The resulting autonomous nonlinear pH curves can be coupled with a variety of pH-sensitive building blocks to program the life cycles of the associated transient state at the level of self-assemblies and material systems. In this article, we discuss the different generations of such pH feedback systems, the principles of their coupling to self-assemblies with lifecycles and highlight emerging concepts for the design of autonomous functional materials. The specificity, robustness, and flexible operation of such pH-FS can also be used to realize chemical-structural and chemical-mechanical feedbacks that extend the behavior of such materials systems toward complex and functional life-like systems." @default.
- W4310033003 created "2022-11-30" @default.
- W4310033003 creator A5044025674 @default.
- W4310033003 creator A5060067635 @default.
- W4310033003 creator A5090588227 @default.
- W4310033003 date "2022-11-28" @default.
- W4310033003 modified "2023-10-16" @default.
- W4310033003 title "pH Feedback Systems to Program Autonomous Self-Assembly and Material Lifecycles" @default.
- W4310033003 doi "https://doi.org/10.26434/chemrxiv-2022-lbppx" @default.
- W4310033003 hasPublicationYear "2022" @default.
- W4310033003 type Work @default.
- W4310033003 citedByCount "0" @default.
- W4310033003 crossrefType "posted-content" @default.
- W4310033003 hasAuthorship W4310033003A5044025674 @default.
- W4310033003 hasAuthorship W4310033003A5060067635 @default.
- W4310033003 hasAuthorship W4310033003A5090588227 @default.
- W4310033003 hasBestOaLocation W43100330031 @default.
- W4310033003 hasConcept C104317684 @default.
- W4310033003 hasConcept C111472728 @default.
- W4310033003 hasConcept C11413529 @default.
- W4310033003 hasConcept C120314980 @default.
- W4310033003 hasConcept C121332964 @default.
- W4310033003 hasConcept C127413603 @default.
- W4310033003 hasConcept C131584629 @default.
- W4310033003 hasConcept C133731056 @default.
- W4310033003 hasConcept C138885662 @default.
- W4310033003 hasConcept C154945302 @default.
- W4310033003 hasConcept C158622935 @default.
- W4310033003 hasConcept C171250308 @default.
- W4310033003 hasConcept C183696295 @default.
- W4310033003 hasConcept C185592680 @default.
- W4310033003 hasConcept C192562407 @default.
- W4310033003 hasConcept C202444582 @default.
- W4310033003 hasConcept C2776184637 @default.
- W4310033003 hasConcept C2780586882 @default.
- W4310033003 hasConcept C33923547 @default.
- W4310033003 hasConcept C41008148 @default.
- W4310033003 hasConcept C47822265 @default.
- W4310033003 hasConcept C48103436 @default.
- W4310033003 hasConcept C55493867 @default.
- W4310033003 hasConcept C62520636 @default.
- W4310033003 hasConcept C63479239 @default.
- W4310033003 hasConcept C78519656 @default.
- W4310033003 hasConcept C9652623 @default.
- W4310033003 hasConceptScore W4310033003C104317684 @default.
- W4310033003 hasConceptScore W4310033003C111472728 @default.
- W4310033003 hasConceptScore W4310033003C11413529 @default.
- W4310033003 hasConceptScore W4310033003C120314980 @default.
- W4310033003 hasConceptScore W4310033003C121332964 @default.
- W4310033003 hasConceptScore W4310033003C127413603 @default.
- W4310033003 hasConceptScore W4310033003C131584629 @default.
- W4310033003 hasConceptScore W4310033003C133731056 @default.
- W4310033003 hasConceptScore W4310033003C138885662 @default.
- W4310033003 hasConceptScore W4310033003C154945302 @default.
- W4310033003 hasConceptScore W4310033003C158622935 @default.
- W4310033003 hasConceptScore W4310033003C171250308 @default.
- W4310033003 hasConceptScore W4310033003C183696295 @default.
- W4310033003 hasConceptScore W4310033003C185592680 @default.
- W4310033003 hasConceptScore W4310033003C192562407 @default.
- W4310033003 hasConceptScore W4310033003C202444582 @default.
- W4310033003 hasConceptScore W4310033003C2776184637 @default.
- W4310033003 hasConceptScore W4310033003C2780586882 @default.
- W4310033003 hasConceptScore W4310033003C33923547 @default.
- W4310033003 hasConceptScore W4310033003C41008148 @default.
- W4310033003 hasConceptScore W4310033003C47822265 @default.
- W4310033003 hasConceptScore W4310033003C48103436 @default.
- W4310033003 hasConceptScore W4310033003C55493867 @default.
- W4310033003 hasConceptScore W4310033003C62520636 @default.
- W4310033003 hasConceptScore W4310033003C63479239 @default.
- W4310033003 hasConceptScore W4310033003C78519656 @default.
- W4310033003 hasConceptScore W4310033003C9652623 @default.
- W4310033003 hasFunder F4320332999 @default.
- W4310033003 hasLocation W43100330031 @default.
- W4310033003 hasOpenAccess W4310033003 @default.
- W4310033003 hasPrimaryLocation W43100330031 @default.
- W4310033003 hasRelatedWork W148869540 @default.
- W4310033003 hasRelatedWork W1978743058 @default.
- W4310033003 hasRelatedWork W1979270397 @default.
- W4310033003 hasRelatedWork W2018074481 @default.
- W4310033003 hasRelatedWork W2088252321 @default.
- W4310033003 hasRelatedWork W2105317715 @default.
- W4310033003 hasRelatedWork W2107556256 @default.
- W4310033003 hasRelatedWork W2356212209 @default.
- W4310033003 hasRelatedWork W2936535786 @default.
- W4310033003 hasRelatedWork W2953090168 @default.
- W4310033003 isParatext "false" @default.
- W4310033003 isRetracted "false" @default.
- W4310033003 workType "article" @default.