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• W4310059425 abstract "Three new triazine compounds [Co1.5(H3TDPAT)(H2O)3]·6H2O (1), [Co2(TCPT)(μ2-H2O)2]·OH (2), and [Ni3(TCPT)]·3OH (3) were designed and synthesized via the reaction of the symmetrical triazine ligand connected by C–N–C and C–O–C bonds with triazine poly(carboxylic acid)s ligands as the side arms: H6TDPAT (H6TDPAT = 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine) and H3TCPT (H3TCPT = 2,4,6-tris(4-carboxyphenoxy)-1,3,5-triazine) as well as the corresponding metal salts under the solvothermal condition. Three triazine polycarboxylate frameworks were characterized by elemental analysis, infrared spectroscopy, ultraviolet spectroscopy, thermogravimetric analysis, X-ray powder diffraction, and solid fluorescent spectra in detail. The structural analysis results showed that the three-dimensional porous cage framework of compound 1 was constructed by three different polyhedral cages connected with [Co(COO)4(H2O)2] building blocks. One of the compounds, 2, is formed by twin propeller Co2(μ2-H2O)(COO)3 building blocks connecting two-dimensional layers and the intermolecular π–π interactions involved the triazine rings between the layers. While the structure of compound 3 is similar to that of 2, assembly is by Ni(COO)3 building blocks and adjacent layers of the face-to-face π–π interaction between the triazine rings. In order to explore functional properties, the catalytic reduction of p-nitrophenol (PNP) of compounds 1–3 was investigated. They exhibit excellent catalytic activity of more than 95% for reduction of PNP with a dose of 2.5 mg of the compounds." @default.
• W4310059425 created "2022-11-30" @default.
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• W4310059425 date "2022-11-25" @default.
• W4310059425 modified "2023-10-18" @default.
• W4310059425 title "High-Symmetry Co/Ni Triazine Polycarboxylate Diverse Frameworks Constructed by M_<i>x</i>(COO)_<i>y</i> Building Blocks: Characterization and Catalytic Performance Evaluation of <i>p</i>-Nitrophenol" @default.
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• W4310059425 doi "https://doi.org/10.1021/acs.inorgchem.2c03233" @default.
• W4310059425 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36426639" @default.
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