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- W4310136434 abstract "The diversity of metallodrugs used as diagnostics and therapeutics in disease treatment and their prevailing side-effects in human metabolism present an urgent need for exploration and development of new metal-based agents. Among them, rare earth metals constitute a unique case when combining with natural binders, such as antioxidant flavonoids. To that end, a multiparametric synthetic investigation of ternary systems of Er(III), Dy(III), Sm(III) with flavone chrysin and N,N’-aromatic chelator (phen) led to crystalline mononuclear materials, which were physicochemically characterized through elemental analysis, FT-IR, UV–Visible, ESI-MS, and X-ray crystallography. The coordination environment of trivalent lanthanides in each assembly reveals the salient features of ternary component binding modes, with the contribution of chrysin to lanthanide coordination validated though BVS and Hirshfeld surface analysis. The structural, electronic, and magnetics data of the new species signify the importance of structural speciation in drawing correlations with optical and magnetic properties, thus formulating well-defined physicochemical profiles and projecting essential attributes linked to the development of new materials of potential diagnostic-therapeutic value." @default.
- W4310136434 created "2022-11-30" @default.
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- W4310136434 date "2023-01-01" @default.
- W4310136434 modified "2023-10-16" @default.
- W4310136434 title "Chemical reactivity profile of rare earth metal ions with flavonoids. From structural speciation to magneto-optical properties" @default.
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- W4310136434 doi "https://doi.org/10.1016/j.poly.2022.116231" @default.
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