FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310189589> ?p ?o ?g. }

• W4310189589 endingPage "8312" @default.
• W4310189589 startingPage "8312" @default.
• W4310189589 abstract "This work is a mini-review highlighting the relevance of the θ metallabis(dicarbollide) [3,3′-Co(1,2-C2B9H11)2]− with its peculiar and differentiating characteristics, among them the capacity to generate hydrogen and dihydrogen bonds, to generate micelles and vesicles, to be able to be dissolved in water or benzene, to have a wide range of redox reversible couples and many more, and to use these properties, in this case, for producing potentiometric membrane sensors to monitor amine-containing drugs or other nitrogen-containing molecules. Sensors have been produced with this monoanionic cluster [3,3′-Co(1,2-C2B9H11)2]−. Other monoanionic boron clusters are also discussed, but they are much fewer. It is noteworthy that most of the electrochemical sensor species incorporate an ammonium cation and that this cation is the species to be detected. Alternatively, the detection of the borate anion itself has also been studied, but with significantly fewer examples. The functions of the borate anion in the membrane are different, even as a doping agent for polypyrrole which was the conductive ground on which the PVC membrane was deposited. Apart from these cases related to closo borates, the bulk of the work has been devoted to sensors in which the θ metallabis (dicarbollide) [3,3′-Co(1,2-C2B9H11)2]− is the key element. The metallabis (dicarbollide) anion, [3,3′-Co(1,2-C2B9H11)2]−, has many applications; one of these is as new material used to prepare an ion-pair complex with bioactive protonable nitrogen containing compounds, [YH]x[3,3′-Co(1,2-C2B9H11)2]y as an active part of PVC membrane potentiometric sensors. The developed electrodes have Nernstian responses for target analytes, i.e., antibiotics, amino acids, neurotransmitters, analgesics, for some decades of concentrations, with a short response time, around 5 s, a good stability of membrane over 45 days, and an optimal selectivity, even for optical isomers, to be used also for real sample analysis and environmental, clinical, pharmaceutical and food analysis." @default.
• W4310189589 created "2022-11-30" @default.
• W4310189589 creator A5032313019 @default.
• W4310189589 creator A5084168197 @default.
• W4310189589 creator A5084236161 @default.
• W4310189589 date "2022-11-29" @default.
• W4310189589 modified "2023-10-16" @default.
• W4310189589 title "History of Cobaltabis(dicarbollide) in Potentiometry, No Need for Ionophores to Get an Excellent Selectivity" @default.
• W4310189589 cites W1531999949 @default.
• W4310189589 cites W153203464 @default.
• W4310189589 cites W1964058875 @default.
• W4310189589 cites W1968885557 @default.
• W4310189589 cites W1970743031 @default.
• W4310189589 cites W1970939924 @default.
• W4310189589 cites W1974829498 @default.
• W4310189589 cites W1977211805 @default.
• W4310189589 cites W1991731865 @default.
• W4310189589 cites W1997696498 @default.
• W4310189589 cites W2004328066 @default.
• W4310189589 cites W2005315898 @default.
• W4310189589 cites W2005540601 @default.
• W4310189589 cites W2010615602 @default.
• W4310189589 cites W2012693372 @default.
• W4310189589 cites W2018587140 @default.
• W4310189589 cites W2019271061 @default.
• W4310189589 cites W2026015567 @default.
• W4310189589 cites W2028991191 @default.
• W4310189589 cites W2037270587 @default.
• W4310189589 cites W2041690888 @default.
• W4310189589 cites W2043499315 @default.
• W4310189589 cites W2050706003 @default.
• W4310189589 cites W2052214146 @default.
• W4310189589 cites W2063378958 @default.
• W4310189589 cites W2070593886 @default.
• W4310189589 cites W2075489519 @default.
• W4310189589 cites W2076187208 @default.
• W4310189589 cites W2077580084 @default.
• W4310189589 cites W2080338862 @default.
• W4310189589 cites W2080427863 @default.
• W4310189589 cites W2082004064 @default.
• W4310189589 cites W2082332887 @default.
• W4310189589 cites W2087789945 @default.
• W4310189589 cites W2089622075 @default.
• W4310189589 cites W2093517718 @default.
• W4310189589 cites W2095256453 @default.
• W4310189589 cites W2107392895 @default.
• W4310189589 cites W2112481330 @default.
• W4310189589 cites W2117783753 @default.
• W4310189589 cites W2119136316 @default.
• W4310189589 cites W2125746135 @default.
• W4310189589 cites W2133435486 @default.
• W4310189589 cites W2134632594 @default.
• W4310189589 cites W2135014518 @default.
• W4310189589 cites W2139897855 @default.
• W4310189589 cites W2141650218 @default.
• W4310189589 cites W2161018367 @default.
• W4310189589 cites W2313875397 @default.
• W4310189589 cites W2323624172 @default.
• W4310189589 cites W2331621503 @default.
• W4310189589 cites W2406091788 @default.
• W4310189589 cites W2553518572 @default.
• W4310189589 cites W2604655487 @default.
• W4310189589 cites W2744675484 @default.
• W4310189589 cites W2748212730 @default.
• W4310189589 cites W2799752600 @default.
• W4310189589 cites W2891488717 @default.
• W4310189589 cites W2943110552 @default.
• W4310189589 cites W2951526299 @default.
• W4310189589 cites W2968601567 @default.
• W4310189589 cites W2994277041 @default.
• W4310189589 cites W3016762617 @default.
• W4310189589 cites W3020711625 @default.
• W4310189589 cites W3081000195 @default.
• W4310189589 cites W3081234447 @default.
• W4310189589 cites W3082777273 @default.
• W4310189589 cites W3112064743 @default.
• W4310189589 cites W3117006211 @default.
• W4310189589 cites W3134215683 @default.
• W4310189589 cites W3158698558 @default.
• W4310189589 cites W4200465180 @default.
• W4310189589 cites W4214809320 @default.
• W4310189589 cites W4220786472 @default.
• W4310189589 cites W4224923245 @default.
• W4310189589 cites W4226412954 @default.
• W4310189589 cites W4246209615 @default.
• W4310189589 cites W4280522854 @default.
• W4310189589 cites W4301239399 @default.
• W4310189589 doi "https://doi.org/10.3390/molecules27238312" @default.
• W4310189589 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36500404" @default.
• W4310189589 hasPublicationYear "2022" @default.
• W4310189589 type Work @default.
• W4310189589 citedByCount "2" @default.
• W4310189589 countsByYear W43101895892023 @default.
• W4310189589 crossrefType "journal-article" @default.
• W4310189589 hasAuthorship W4310189589A5032313019 @default.
• W4310189589 hasAuthorship W4310189589A5084168197 @default.
• W4310189589 hasAuthorship W4310189589A5084236161 @default.
• W4310189589 hasBestOaLocation W43101895891 @default.

• next