Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310204412> ?p ?o ?g. }
- W4310204412 endingPage "224" @default.
- W4310204412 startingPage "224" @default.
- W4310204412 abstract "The dimeric gold(I) chloride and gold(I) iodide complexes ([L2Au]Cl2 and L2AuI2) on the scaffold of the cyclic bisphosphine, namely 1,5-diaza-3,7-diphosphacyclooctane containing α-phenylbenzyl (benzhydryl) substituents at the nitrogen atoms, were synthesized. The obtained complexes were isolated as white crystalline powders. The single crystal XRD of the obtained complexes revealed the strong aurophilic interactions between two gold(I) atoms with the Au…Au distance values of 2.9977(6) and 3.1680(5) Å. The comparison of the gold complexes, based on the N,N-diaryl- and N,N-dibenzhydryl substituted 1,5-diaza-3,7-diphosphacyclooctanes, allowed to reveal the strong impact of the initial heterocycle conformation on the realization of the aurophilic interactions, where the geometry of N,N-dibenzhydryl substituted 1,5-diaza-3,7-diphosphacyclooctane, is pre-organized for the intramolecular aurophilic interactions of the complexes. The obtained complexes exhibit a bluish-green phosphorescence (λem 505 (-Cl) and 530(-I)) in the solid state at room temperature, originated by the metal-halide centered transitions, which was confirmed by the TDDFT calculations. It was found that the aurophilic interactions are realized in the ground and in the triplet excited states of the complexes. The slighter change of the geometry of the N,N-dibenzhydryl substituted gold(I) iodide complexes, under the transition from the ground state to the excited state, in comparison with their N,N-diaryl substituted analogues, results in the reduced values of the Stokes shift of luminescence (ca. 150 nm vs. 175 nm)." @default.
- W4310204412 created "2022-11-30" @default.
- W4310204412 creator A5000984436 @default.
- W4310204412 creator A5003789092 @default.
- W4310204412 creator A5006498774 @default.
- W4310204412 creator A5016339316 @default.
- W4310204412 creator A5052594437 @default.
- W4310204412 creator A5059712951 @default.
- W4310204412 creator A5071347106 @default.
- W4310204412 creator A5091561362 @default.
- W4310204412 creator A5028234473 @default.
- W4310204412 date "2022-11-25" @default.
- W4310204412 modified "2023-10-14" @default.
- W4310204412 title "Aurophilic Interactions of Dimeric Bisphosphine Gold(I) Complexes Pre-Organized by the Structure of the 1,5-Diaza-3,7-Diphosphacyclooctanes" @default.
- W4310204412 cites W1978577971 @default.
- W4310204412 cites W1986628846 @default.
- W4310204412 cites W1987443783 @default.
- W4310204412 cites W1988091937 @default.
- W4310204412 cites W1990170643 @default.
- W4310204412 cites W1999371754 @default.
- W4310204412 cites W2004123744 @default.
- W4310204412 cites W2008423326 @default.
- W4310204412 cites W2013131406 @default.
- W4310204412 cites W2021200484 @default.
- W4310204412 cites W2024175762 @default.
- W4310204412 cites W2028117546 @default.
- W4310204412 cites W2030841140 @default.
- W4310204412 cites W2032500472 @default.
- W4310204412 cites W2044077218 @default.
- W4310204412 cites W2061393179 @default.
- W4310204412 cites W2080709819 @default.
- W4310204412 cites W2092157292 @default.
- W4310204412 cites W2096747776 @default.
- W4310204412 cites W2099408761 @default.
- W4310204412 cites W2103438584 @default.
- W4310204412 cites W2105528285 @default.
- W4310204412 cites W2131350133 @default.
- W4310204412 cites W2149077679 @default.
- W4310204412 cites W2156847578 @default.
- W4310204412 cites W2280629688 @default.
- W4310204412 cites W2283718982 @default.
- W4310204412 cites W2314265222 @default.
- W4310204412 cites W2320755284 @default.
- W4310204412 cites W2340739754 @default.
- W4310204412 cites W2518201702 @default.
- W4310204412 cites W2518748273 @default.
- W4310204412 cites W2527830063 @default.
- W4310204412 cites W2596692110 @default.
- W4310204412 cites W2614372380 @default.
- W4310204412 cites W2761270158 @default.
- W4310204412 cites W2770074049 @default.
- W4310204412 cites W2786896733 @default.
- W4310204412 cites W2895547729 @default.
- W4310204412 cites W2907666262 @default.
- W4310204412 cites W2960007360 @default.
- W4310204412 cites W2993088861 @default.
- W4310204412 cites W2994688699 @default.
- W4310204412 cites W3005853354 @default.
- W4310204412 cites W3042582358 @default.
- W4310204412 cites W3042632890 @default.
- W4310204412 cites W3047083446 @default.
- W4310204412 cites W3137834368 @default.
- W4310204412 doi "https://doi.org/10.3390/inorganics10120224" @default.
- W4310204412 hasPublicationYear "2022" @default.
- W4310204412 type Work @default.
- W4310204412 citedByCount "0" @default.
- W4310204412 crossrefType "journal-article" @default.
- W4310204412 hasAuthorship W4310204412A5000984436 @default.
- W4310204412 hasAuthorship W4310204412A5003789092 @default.
- W4310204412 hasAuthorship W4310204412A5006498774 @default.
- W4310204412 hasAuthorship W4310204412A5016339316 @default.
- W4310204412 hasAuthorship W4310204412A5028234473 @default.
- W4310204412 hasAuthorship W4310204412A5052594437 @default.
- W4310204412 hasAuthorship W4310204412A5059712951 @default.
- W4310204412 hasAuthorship W4310204412A5071347106 @default.
- W4310204412 hasAuthorship W4310204412A5091561362 @default.
- W4310204412 hasBestOaLocation W43102044121 @default.
- W4310204412 hasConcept C121332964 @default.
- W4310204412 hasConcept C148869448 @default.
- W4310204412 hasConcept C171560689 @default.
- W4310204412 hasConcept C179104552 @default.
- W4310204412 hasConcept C181500209 @default.
- W4310204412 hasConcept C181817918 @default.
- W4310204412 hasConcept C185544564 @default.
- W4310204412 hasConcept C185592680 @default.
- W4310204412 hasConcept C192562407 @default.
- W4310204412 hasConcept C2778870691 @default.
- W4310204412 hasConcept C49040817 @default.
- W4310204412 hasConcept C62520636 @default.
- W4310204412 hasConcept C71240020 @default.
- W4310204412 hasConcept C75079739 @default.
- W4310204412 hasConcept C75473681 @default.
- W4310204412 hasConcept C8010536 @default.
- W4310204412 hasConcept C91881484 @default.
- W4310204412 hasConceptScore W4310204412C121332964 @default.
- W4310204412 hasConceptScore W4310204412C148869448 @default.
- W4310204412 hasConceptScore W4310204412C171560689 @default.
- W4310204412 hasConceptScore W4310204412C179104552 @default.